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Zinc Carbonate Hydroxide CAS 12539-71-8

Molecular Formula: CH2O4Zn-2

Formula Weight: 143.4

ZSpharmac: Zinc Carbonate Hydroxide Raw Material Supplier

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Product Name: Zinc Carbonate Hydroxide
CAS No: 12539-71-8
Purity: 99%

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Basic Info

Product Name:Zinc Carbonate Hydroxide
Other Names:Zinc Carbonate Basic
CAS:12539-71-8
Place of Origin:Shandong, China
Brand Name:ZSpharmac
Type:Cosmetic Raw Materials
Appearance:White Powder
EINECS No.:226-076-7
Storage:2-8°C
Provide:Zinc Carbonate Hydroxide MSDS;
Zinc Carbonate Hydroxide COA

What is Zinc Carbonate Hydroxide?

Zinc Carbonate Hydroxide is a white amorphous powder that has a relative density ranging from 4.42 to 4.45. It can be dissolved in dilute acids and alkali, but only slightly soluble in ammonia and ammonium salts. However, it remains insoluble in water, ethanol, and acetone. When exposed to a temperature of 300℃, it decomposes and forms carbon dioxide and zinc oxide. Additionally, when it reacts with H2O2, it releases CO2 and forms peroxide. If heated between 250 to 500°C for varying durations and subsequently cooled to room temperature, it may exhibit fluorescence.

This compound finds various applications, such as in the production of latex film products, pigments, rayon, catalytic desulfurizers, and medicinal uses including light astringents, preservatives, disinfectants, and skin protectants.

Zinc Carbonate Hydroxide Property

Melting point 300 °C (dec.)(lit.)
Merck 14,10131
Stability:Stable. Hygroscopic. Incompatible with strong acids, strong oxidizing agents.

 

Zinc Carbonate Hydroxide Drying Method

The traditional method of drying Zinc Carbonate Hydroxide involves using thermal energy sources like coal, oil, or natural gas. This process often leads to a significant waste of energy and the release of harmful gases such as carbon dioxide and sulfur dioxide, which is detrimental to both energy conservation and environmental protection.

For instance, some manufacturers use coal-fired boiler steam to indirectly dry basic zinc carbonate. This method consumes 0.7 tons of standard coal and emits 2.6 tons of carbon dioxide and 8.5 kilograms of sulfur dioxide per ton of dried product. If a factory produces 3 tons of basic zinc carbonate daily, it would emit 5.6 tons of carbon dioxide and 18 kilograms of sulfur dioxide waste gases each day. These emissions contribute to haze weather conditions and contradict current energy conservation and environmental protection policies.

To address these issues, CN201410401834.3 proposes a drying device for Zinc Carbonate Hydroxide. This device solves the problems associated with energy waste and environmental unfriendliness in the drying process. The device consists of a drying chamber and a solar water heater. A drying bed is positioned beneath the drying chamber, comprising a thermally conductive metal plate, a water pipe, and a foam insulation board. The output end of the solar water heater is connected to one end of the water pipe through a hot water delivery pipe, while the other end of the water pipe is connected to the input of the solar water heater through a return pipe.

The working principle of this device is as follows:
1. The basic zinc carbonate material containing moisture is placed on the heat-conducting metal plate of the drying bed in the drying chamber and spread out.
2. Outdoor sunlight passes through the plastic film or glass on the top and sides of the drying chamber, radiating onto the upper surface of the drying bed and reaching the basic zinc carbonate material.
3. Simultaneously, hot water from the solar water heater enters the heat dissipation pipe in the drying bed through the hot water delivery pipe, facilitated by a hot water circulation pump.
4. The heat generated by the heat dissipation pipe is transferred to the lower surface of the basic zinc carbonate material through the heat-conductive metal plate, effectively heating and drying both surfaces of the material.
5. The moisture generated during the drying process is expelled through the windows on the top and sides of the drying chamber, accelerating the drying speed.
6. The cooled hot water in the radiating water pipe flows back to the solar water heater through the return pipe, where it is reheated. This cycle continues, ensuring a continuous supply of heated water to dry the materials on the drying bed.
7. As the Zinc Carbonate Hydroxide products are not affected by high temperatures when exposed to sunlight, the quality of the dried product remains unchanged.

By utilizing solar energy and a more efficient drying process, this device significantly reduces energy waste and emissions, aligning with energy conservation and environmental protection goals.

Zinc Carbonate Hydroxide Preparation

A production method for Zinc Carbonate Hydroxide involves the following steps:

(1) Zinc suboxide is added to a sulfuric acid solution and the reaction is stirred to produce a zinc sulfate solution.

The chemical equation for this reaction is:

ZnO + H2SO4 = ZnSO4 + H2O

During this reaction, some by-products are generated, including:

PbO + H2SO4 = PbSO4↓ + H2O (PbSO4 precipitates as a solid)

FeO + H2SO4 = FeSO4 + H2O

CuO + H2SO4 = CuSO4 + H2O

CdO + H2SO4 = CdSO4 + H2O

MnO + H2SO4 = MnSO4 + H2O

(2) Potassium permanganate and zinc powder are added to the zinc sulfate solution to remove impurities and obtain an impurity-free zinc sulfate solution.

The addition of potassium permanganate can remove divalent iron and manganese ions in the reaction solution, resulting in the removal of FeSO4 and MnSO4. The reaction equations are:

2H2O + 3MnSO4 + 2KMnO4 = K2SO4 + 5MnO2↓ + 2H2SO4

14H2O + 6FeSO4 + 2KMnO4 = K2SO4 + 6Fe(OH)3↓ + 5H2SO4 + 2MnO2↓

MnSO4 reacts with potassium permanganate to form manganese dioxide precipitate, which removes manganese ions. FeSO4 reacts with potassium permanganate to form iron hydroxide precipitate, which removes iron ions.

(3) Sodium carbonate solution is added to the impurity-free zinc sulfate solution, and the reaction is stirred at a temperature of 50-55°C until the pH of the solution reaches 6.5-7.5. The reaction is then continued at a temperature of 45-65°C for 0.5-1 hour.

The chemical equation for the reaction between zinc sulfate and sodium carbonate is:

3ZnSO4 + 3Na2CO3 + 3H2O = ZnCO3·2Zn(OH)2·H2O + 3Na2SO4 + 2CO2↑

Once the pH of the solution reaches 6.5-7.5, the reaction is stirred for an additional 0.5-1 hour at a temperature of 45-65°C to ensure complete mixing and reaction of zinc sulfate and sodium carbonate.

(4) The reaction solution is filtered, and the filter cake is washed with purified water until the filtrate no longer contains sulfate ions. The filter cake is then dried and pulverized to obtain basic zinc carbonate. Washing the filter cake with water removes water-soluble impurities, such as sulfate radicals, as basic zinc carbonate is insoluble in water.

Contact Us

About Products:
If you need Zinc Carbonate Hydroxide, a cosmetic raw material, please contact our service staff directly and we will provide you with high-quality products at the best price.
Our company, as an experienced Zinc Carbonate Hydroxide manufacturer and supplier, ZSpharmac will provide Zinc Carbonate Hydroxide raw materials to customers around the world for a long time.
Over the years, the company has adhered to the spirit of “integrity management, strict quality control, and customer first” and has won unanimous praise from customers at home and abroad.

Company Profile and Corporate Culture

Company Profile:

ZhiShang Chemical is owned by ZhiShang Group is a professional new-type chemicals enterprise combined into research and development, production and sales .

The company’s competitive product is pharmaceutical raw materials and intermediates (especially carbohydrate derivatives Series), In recent years, the company has made a major breakthrough in food and feed additives, plant extraction, industrial chemicals industry .

The company insists on the spirit of “sincere management, strict quality control, customer as god” , get consistent high praise from customers at home and abroad.

Corporate Culture:

OUR MISSION
Help China Chemicals to benefit the happiness of human life
OUR VISSION
Become the most trusted chemical supplier in the world
OUR BUSINESS PHILOSOPHY
Striver – oriented, enrich employees, customer first, deep service, seek development
OUR VALUES
Be prepared for danger in times of peace, forge ahead actively, unity and cooperation, and be brave to fight

About Us

The production base is located in Zhangqiu chemical industry park and Tai’an high-tech chemical industry park. laboratory and workshop in strict accordance with the GMP standard and the product fit national ISO9001 and ISO2000 standards.

“Zhishang” products are exported to Europe, North and South America, the Middle East, Asia Pacific and Africa area, so as to establish a long-term and stable cooperation relationship with customer in the world.

Company Info
  • Business Type: Manufacturer
  • Product Range: Cosmetic raw materials
  • Products/Service:Cosmetic raw materials (flavors and fragrances,antioxidant products, moisturizing and hydrating, whitening agents, cosmetic additives)
  • Total Employees: 51~100
  • Capital (Million US $): 10000000RMB
  • Year Established: 2016
Production Capacity
  • No. of Production Lines : 8
  • No. of QC Staff : 5 -10 People
  • OEM Services Provided : yes
  • Factory Size (Sq.meters) : 3,000-5,000 square meters
  • Certificate: ISO9001 , CE , GMP , API , MSDS
  • Factory Location : Diao Town Industry Park, Zhangqiu City, Jinan City, Shandong Province, China.

Service

Pre-Sales Service

* Prompt reply and 24 hours online, professional team to provide best price and high quality product.

* Sample testing support.

* Every batch of products will be tested to ensureits quality.

*The packing also can be according the customers` requirment.

*Any inquiries will be replied within 24 hours.

*we provide Commerical Invoice, Packing List, Bill of loading, COA , Health certificate and Origin certificate. If your markets have any special requirements, let us know.

 

After-Sales Service

*The fact of logistics information monitoring.

* Any questions about the product can be consulted at any time.

*Product has any problem can return.

FAQ

Do you accept sample order?

We will make samples before mass production, and after sample approved, we’ll begin mass production. Doing 100% inspection during production, then do random inspection before packing.

 

HOW TO CONFIRM THE PRODUCT QUALITY BEFORE PLACING ORDERS?

You can get free samples for some products,you only need to pay the shipping cost or arrange a courier to us and take the samples. You can send us your product specifications and requests,we will manufacture the products according to your requests.

What’s your MOQ?

Our MOQ is 1kg. But usually we accept less quantity such as 100g on the condition that sample charge is 100% paid.

Do you supply product report?

Yes. We’ll give you product analysis report before shipping.

  Is there a discount?

Different quantity has different discount.

Shipping

1. ≤50kg, Express delivery recommended, usually called as DDU service;

2. ≤500kg, Air shipping recommended, usually called as FOB, CFR, or CIF service;

3. >500kg, sea shipping recommended, usually called as FOB, CFR, or CIF service;

4. For high value products, please select air shipping and express delivery for safe.

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