Zhishang Chemical

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Zhishang Chemical

Undecanal CAS 112-44-7

Molecular Formula: C11H22O

Formula Weight: 170.29

ZSpharmac: Undecanal Supplement

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Product Name: Undecanal
CAS No: 112-44-7
Purity: 99%

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Basic Info

Product Name:Undecanal
Other Names:Undecanal, 97%
CAS:112-44-7
Place of Origin:Shandong, China
Brand Name:ZSpharmac
Type:Cosmetic Raw Materials
Appearance:Slightly Yellow Oily Liquid
EINECS No.:203-972-6
Storage:Inert atmosphere,2-8°C
Provide:Undecanal MSDS;
Undecanal COA

What is Undecanal?

Undecanal is also referred to as Undecyl aldehyde. Colorless to slightly yellow oily liquid. Oily smell, orange and rose-like scent after dilution. Pleasant. Takes place naturally in orange and also lemon oils. The relative molecular mass is 170.32. The family member density is 0.8251 (25 ° C). Melting point -4 ° C, boiling point 223 ° C, 120 ° C (2.666 × 103Pa), 117 ° C (2.400 × 103Pa), 109 ~ 115 ° C (0.667 × 103Pa). Refractive index 1.4520. Flash point 96 ℃. Insoluble in water as well as glycerol, soluble in common organic solvents such as ethanol as well as propylene glycol.

It is unstable in both acidic and alkaline media. Easy to polymerize in air. Utilizes: Spices. Prepare climbed, tuberose, jasmine and various other flower-flavored tastes for cosmetics as well as soap flavors; as edible tastes allowed by my nation’s GB2760-1996 regulations, prepare lemon, orange, orange and other fruit-based tastes for food.

Undecanal Properties

Melting point 

-2 °C (lit.)

Boiling point 

109-115 °C/5 mmHg (lit.)

density 

0.825 g/mL at 25 °C (lit.)

vapor density 

5.94 (vs air)

refractive index 

n20/D 1.4322(lit.)

Fp 

205 °F

storage temp. 

Inert atmosphere,2-8°C

form 

neat

explosive limit

0.7%(V)

Water Solubility 

Soluble in dipropylene glycol, fixed oils, propylene glycol and water (14.27 mg/L at 25°C)

 

Undecanal Uses

  1. Undecanal is widely used in fragrance formulations. A small amount (<0.5%) is used for rose, tuberose, acacia, orange blossom, jasmine, iris and other floral scents. Can also be used as a top note for citrus and other fruity aromas. Also used in fantasy fragrances. It can be used in the preparation of lemon, white lemon, orange, orange, cucumber, honey, fresh and various fruit-flavor compounds and gum flavors.
  2. Undecanalshi GB 2760–1996 stipulates that it is allowed to use edible spices. It is mainly used to prepare flavors from lemons, lemons, oranges and other citrus and cucumber, honey and gum.
  3. Undecanal has rose fragrance in diluted state; floral fragrance; fruit fragrance and sweet orange fragrance, used as a floral fragrance extracting agent, used in cosmetics; in soap essence.

Undecanalde App

Methylnonylacetal is an important raw material for the preparation of modern fragrances, with aldehyde aromas accompanied by ambergris, citrus and vanilla aromas. Because of its strong aroma, good diffusivity and long fragrance retention time, it is often used as the top incense for aldehyde aroma, and can also be used for the preparation of tobacco, amber and other flavors. In addition, it can also be used directly as a raw material for cosmetics and food flavors. CN201810211803.X provides a method for synthesizing methyl nonacetaldehyde.

Including (a) using n-Undecanal and formaldehyde as raw materials in solvent methanol, using morpholine/acetic acid as catalyst, wherein n-undecanal is added dropwise into the reaction system, and reacted at 70-80 ℃ to form sub- Methylundecanal; (b) using methyleneundecanal as raw material, palladium/carbon as catalyst, hydrogenation reaction to generate methylnonacetaldehyde. The synthetic equation of this synthetic method is:

The present invention adopts morpholine/acetic acid as the catalyst for the aldol reaction, the reaction conditions are mild, and the selectivity is high. Further, the present invention adopts the dropwise addition method to add n-undecanal, reduces the generation of side reactions, and improves the selectivity and yield of the reaction; Sex is high. It has the advantages of high reaction selectivity and high yield.

The existing environmental protection wall coatings are divided into water-based latex coatings and oil-based environmental protection wall coatings. The construction of water-based latex paint is greatly affected by temperature, so it cannot be applied in colder areas, and it also has requirements on humidity. When the humidity is high, the drying period is too long. In addition, the existing water-based latex coatings have poor anti-fouling performance, do not have good water resistance and wear resistance, are easy to chalk, fade, have poor anti-aging properties, and have problems such as low gloss of the coating film. CN201511015561.X provides a durable new latex paint and a preparation method thereof, which have the advantages of less volatile organic compound content, less environmental pollution, energy saving, emission reduction, low carbon and environmental protection.

In order to solve the above-mentioned technical problems, the technical scheme adopted in the present invention is that a durable new latex paint is made from the following raw materials in parts by weight: 15-22 parts of white latex, 3- 7 parts, 2.5-6.8 parts of light calcium carbonate, 10-30 parts of deionized water, 2.5-3.7 parts of oxalic acid, 2.5-6.8 parts of Undecanal and 3.8-9.5 parts of ethyl 2-chloro-3-oxobutyrate. Optimized, the above-mentioned durable new latex paint is made from the following raw materials in parts by weight: 19 parts of white latex, 5 parts of 5-methyl-1-hexanol, 4.2 parts of light calcium carbonate, 18 parts of deionized water, 3.1 parts of oxalic acid, 4.2 parts of Undecanal and 6.9 parts of ethyl 2-chloro-3-oxobutyrate.

Compared with the existing product, the present invention improves the mildew resistance and scrub resistance of the latex paint after mixing oxalic acid, Undecanal and ethyl 2-chloro-3-oxobutyrate, improves the life of the finished latex paint, and can Widely used for wall painting.

CN200810158983.6 provides a kind of rose essence for lip balm which has the advantages of very little dosage, pure and rich fragrance and strong durability.

The rose essence for lip balm of the present invention is refined by adopting the components and weight percentages of the following formulas: ethyl citronellal 0.8%-1.0%, hydroxycitronellal 5.0%-6.0%, Hexalaldehyde 1.0%~1.3%, ketone musk 0.9%~1.1%, musk 1.0%~1.1%, rose 2.0%~2.3%, citronellyl acetate 1.0%~1.1%, geranyl acetate 2.0%~2.2% , Geranyl butyrate 1.8%~2.0%, Phenylacetic acid 0.1%~0.2%, Agaryl acetate 4.0%~4.5%, Geraniol 20.0%~22.0%, Vanillyl alcohol 10.0%~12.0%, Agaryl alcohol 5.0%~6.0%, rositol 5.0%~6.0%, cinnamyl alcohol 2.0%~2.5%, phenethyl alcohol 20.0%~22.0%, geraniol 10.0%~11.0%, nerol 3.5%~4.0%. The advantages of the present invention are: the lip balm of the above formula has convenient source of raw materials of rose essence, pure and rich fragrance, strong persistence, and very little dosage, and the general dosage is 0.5%-1.0%.

Undecanal Preparation

① It can be obtained by oxidation of undecanol or reduction of undecanoic acid.

② It can be prepared by catalytic hydrogenation of methyl undecenoate to produce undecanol, and afterwards catalytic dehydrogenation under the activity of copper driver.

③ Utilizing α-hydroxylauric acid as basic material, it can be gotten by catalytic oxidation.

④ Hydrogenation of methyl undecenoate, a by-product in the preparation of n-heptaldehyde, to produce undecanol, which is after that prepared according to the ② approach or the ① technique.

Company Profile and Corporate Culture

Company Profile:

ZhiShang Chemical is owned by ZhiShang Group is a professional new-type chemicals enterprise combined into research and development, production and sales .

The company’s competitive product is pharmaceutical raw materials and intermediates (especially carbohydrate derivatives Series), In recent years, the company has made a major breakthrough in food and feed additives, plant extraction, industrial chemicals industry .

The company insists on the spirit of “sincere management, strict quality control, customer as god” , get consistent high praise from customers at home and abroad.

Corporate Culture:

OUR MISSION
Help China Chemicals to benefit the happiness of human life
OUR VISSION
Become the most trusted chemical supplier in the world
OUR BUSINESS PHILOSOPHY
Striver – oriented, enrich employees, customer first, deep service, seek development
OUR VALUES
Be prepared for danger in times of peace, forge ahead actively, unity and cooperation, and be brave to fight

About Us

The production base is located in Zhangqiu chemical industry park and Tai’an high-tech chemical industry park. laboratory and workshop in strict accordance with the GMP standard and the product fit national ISO9001 and ISO2000 standards.

“Zhishang” products are exported to Europe, North and South America, the Middle East, Asia Pacific and Africa area, so as to establish a long-term and stable cooperation relationship with customer in the world.

Company Info
  • Business Type: Manufacturer
  • Product Range: Additive , Chemical Auxiliary & Catalyst , Organic Chemicals
  • Products/Service: Organic Intermediate,Inorganic Chemistry, APIs, Dyestuffs And Pigments, Fragrance And Spices, Food Additives
  • Total Employees: 51~100
  • Capital (Million US $): 10000000RMB
  • Year Established: 2016
Production Capacity
  • No. of Production Lines : 8
  • No. of QC Staff : 5 -10 People
  • OEM Services Provided : yes
  • Factory Size (Sq.meters) : 3,000-5,000 square meters
  • Certificate: ISO9001 , CE , GMP , API , MSDS
  • Factory Location : Diao Town Industry Park, Zhangqiu City, Jinan City, Shandong Province, China.

Service

Pre-Sales Service

* Prompt reply and 24 hours online, professional team to provide best price and high quality product.

* Sample testing support.

* Every batch of products will be tested to ensureits quality.

*The packing also can be according the customers` requirment.

*Any inquiries will be replied within 24 hours.

*we provide Commerical Invoice, Packing List, Bill of loading, COA , Health certificate and Origin certificate. If your markets have any special requirements, let us know.

 

After-Sales Service

*The fact of logistics information monitoring.

* Any questions about the product can be consulted at any time.

*Product has any problem can return.

FAQ

Do you accept sample order?

We will make samples before mass production, and after sample approved, we’ll begin mass production. Doing 100% inspection during production, then do random inspection before packing.

 

HOW TO CONFIRM THE PRODUCT QUALITY BEFORE PLACING ORDERS?

You can get free samples for some products,you only need to pay the shipping cost or arrange a courier to us and take the samples. You can send us your product specifications and requests,we will manufacture the products according to your requests.

What’s your MOQ?

Our MOQ is 1kg. But usually we accept less quantity such as 100g on the condition that sample charge is 100% paid.

Do you supply product report?

Yes. We’ll give you product analysis report before shipping.

  Is there a discount?

Different quantity has different discount.

Shipping

1. ≤50kg, Express delivery recommended, usually called as DDU service;

2. ≤500kg, Air shipping recommended, usually called as FOB, CFR, or CIF service;

3. >500kg, sea shipping recommended, usually called as FOB, CFR, or CIF service;

4. For high value products, please select air shipping and express delivery for safe.

Get Undecanal Quotation