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Zhishang Chemical

Pure Oleic Acid CAS 112-80-1

Molecular Formula: C18H34O2

Formula Weight: 282.46

ZSpharmac: Pure Oleic Acid Supplement

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Product Name: Pure Oleic Acid
CAS No: 112-80-1
Purity: 99%

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Basic Info

Product Name:Pure Oleic Acid
Other Names:High Oleic
CAS:112-80-1
Place of Origin:Shandong, China
Brand Name:ZSpharmac
Type:Cosmetic Raw Materials
Appearance:Colorless to Pale Yellow Liquid
EINECS No.:204-007-1
Storage:-20°C
Provide:Pure Oleic Acid MSDS;
Pure Oleic Acid COA

What is Pure Oleic Acid?

Pure Oleic Acid is an unsaturated fat with a carbon-carbon dual bond in its molecular framework, which is the fatty acid that composes olein. Amongst one of the most prevalent kinds of normally occurring unsaturated fatty acids. Pure Oleic Acid can be gotten by oil hydrolysis, and additionally its chemical formula is CH3(CH2)7CH=CH(CH2)7 · COOH. Glycerides of oleic acid are among the main aspects of olive oil, hand oil, lard and numerous other pet dog as well as also vegetable oils. Business products often consist of 7-12% saturated fatty acids (palmitic acid, stearic acid) in addition to a percentage of various other unsaturated fats (linoleic acid). Anemic oily fluid. Specific gravity 0.895 (25/25 ° C). Freezing point 4 ℃. The boiling point of 286 ° C (13,332 ). Refractive index 1.463 (18 ° C). The iodine well worth is 89.9 as well as the acid well worth is 198.6. Insoluble in water, soluble in alcohol, benzene, chloroform, ether as well as likewise other uncertain or set oils. When exposed to the air, specifically when it includes some contaminations, it is conveniently oxidized, the shade turns yellow or brown, as well as it has a rancid smell. It breaks down when warmed to 80-100 ° C under normal tension. It is obtained by saponification as well as acidification of animal and also veggie oils. Oleic acid is an important nutrient in animal food. Its lead, manganese and cobalt salts are paint driers; copper salts are preservatives for angling nets; light weight light weight aluminum salts can be made use of as textile water repellents and also thickeners without a doubt lubricating oils. Oleic acid is epoxidized to develop epoxidized oleate (plasticizer). Oxidative cracking to generate azelaic acid (resources of polyamide product). Airtight, dark storage space.
Pure Oleic Acid is mostly existing in pet along with vegetable oils as well as fats in the form of glycerides. Some very easy oleates are utilized in the material, natural leather, cosmetic and additionally pharmaceutical markets. The alkali steel salt of oleic acid liquifies in water and is simply one of the primary parts of soap. Lead, copper, calcium, mercury, zinc as well as numerous other salts of oleic acid are insoluble in water as well as can be made use of as completely dry lubricating substances, paint driers along with water repellents.
Pure Oleic Acid is mostly originated from nature, in addition to oleic acid can be obtained by saponification, acidification and also splitting up of oils as well as fats with high oleic acid web content. Oleic acid has cis-trans isomers, as well as all-natural oleic acid is a cis-structure (trans-structure can not be soaked up by the body), which has a particular effect on softening blood vessels, along with similarly plays an essential duty in the metabolic rate of individuals as well as likewise animals, however the body itself Synthetic oleic acid can not meet the demands as well as need to be ingested from food, so it benefits health and wellness to take in cooking oil with a high content of oleic acid.

Pure Oleic Acid Property

Melting point 

13-14 °C(lit.)

Boiling point 

360 °C

density 

0.89 g/mL at 25 °C(lit.)

vapor density 

1.03 (vs air)

vapor pressure 

52 mm Hg ( 37 °C)

refractive index 

n20/D 1.377

Fp 

133 °F

storage temp. 

-20°C

solubility 

Miscible with ethanol, ether, acetone, chloroform, dimethyl formamide and dimethyl sulfoxide.

form 

Liquid

pka

pKa 5.35(H2O,t =25) (Uncertain)

color 

Colorless to pale yellow

Specific Gravity

0.892 (20/4℃)

Odor

Peculiar Lard-Like

Water Solubility 

negligible

 

Pure Oleic Acid Uses

  1. The salt or potassium salt of oleic acid is just among the active ingredients of soap. Salt Pure Oleic Acid has terrific discolor removal power and also can be utilized as a surfactant such as an emulsifier. The lead, manganese and likewise cobalt salts of Pure Oleic Acid are paint driers; copper salts are fishnet preservatives; aluminum salts are utilized as fabric water repellents as well as also thickeners without a doubt lubricating oils. Different various other steel salts of oleic acid can furthermore be used in polishing reps, and so on, in addition to its barium salts can be made use of as rodenticides. Pure Oleic Acid is epoxidized to make epoxidized oleate (plasticizer). Azelaic acid is prepared by oxidation, which is the raw product of polyamide material (nylon). Polymerization to produce dimer acid, manufacture of semi-drying alkyd product paints, paints, inks, layers. It can be made use of as a resources for plastic plasticizers, design plastics, synthetic fibers, nylon 8 along with 9, soft hemp representatives, timber preservative ingredients, natural leather accessories, various fabric oil active ingredients, as well as likewise completing representatives; it can be made use of in the manufacturing of synthetic detergents, cleaning Soap, emulsifier S-80, different aesthetic surfactants as well as dispersants; used as printing ink solvent,compound glue; can be utilized as collection agency as well as demulsifier for mineral processing; can additionally be used on duty oil, rolling oil, hydraulic Oil, steel reducing oil and also other steel working as well as lubricating substances.
  2. The woollen textile sector is used to prepare antistatic representatives as well as lubricating softeners. The timber industry is utilized to prepare water repellent paraffin emulsions. It can additionally be used as pesticide emulsifier, lubricating substance, printing and dyeing accessories, commercial solvent, metal mineral flotation protection agent, mold and mildew release agent, oil hydrolysis representative, and also used to prepare carbon paper, typing paper, ballpoint pen oil and also different oleates, and so on. As a chemical reagent, used as a chromatographic contrast example and for biochemical study, it is used to confirm calcium, ammonia, copper, as well as establish magnesium, sulfur, and so on. Activates healthy protein kinases in hepatocytes. A 75% alcohol remedy of Pure Oleic Acid can be made use of as a corrosion cleaner.

Production Process of Pure Oleic Acid

1. Pure Oleic Acid, along with other fats, exists in all animal as well as vegetable oils in the form of glycerides. In animal fats, oleic acid represent regarding 40-50% of fatty acids. The content of vegetable oil differs considerably, as high as 83% in tea oil, 54% in peanut oil, as well as just 5-6% in coconut oil. Oleic acid is a co-product in the production of stearic acid, and both industrial stearic acid as well as industrial oleic acid in fact include other fatty acids. There are several oil as well as fat resources made use of for the manufacturing of stearic acid and Pure Oleic Acid. In industry, combined oil formulas are normally utilized, such as 30% thawed tallow, 10% melted lard, 40% bone fat and also 20% cottonseed oil. Amongst the mixed fatty acids gotten by refining and also hydrolysis of oils and also fats, the melting point of saturated acid as well as unsaturated acid is fairly various. The returns of stearic acid and oleic acid are generally determined by the solution of oil esters. As a whole, cold pushing can obtain 30-50% oleic acid and 50-70% stearic acid. The animal as well as grease and solution are hydrolyzed at 105 ° C, detoxified with stearic acid, and the stearic acid is eliminated by pushing once to get crude oleic acid, which is dried out, distilled and iced up. After additional pushing, palmitic acid is eliminated, and also finally the finished item is obtained by dehydration and refining. This technique can co-produce stearic acid. In a similar way, when stearic acid is generated from oleic acid, oleic acid will likewise be co-produced. Resources consumption quota: pet as well as grease 1950kg/t, sulfuric acid (98%) 210kg/t.

2. Use oils and also fats containing a certain quantity of Pure Oleic Acid as basic materials, such as tallow, lard, and also hand oil, to decay fats, dissolve and cool the fats with a solvent, and eliminate strong fats to obtain crude oleic acid. Liquify with solvent as well as cool at low temperature level to crystallize Pure Oleic Acid.

Refining technique: recrystallize with acetone at -10 ~ -60 ℃, and oleic acid can be separated from linoleic acid and saturated fatty acid. Recurring saturated fatty acids can be sped up by the development of lead salts in ethanol, and afterwards purified by purification. Normally, readily offered oleic acid can be crystallized with acetone at -11 ° C, and also the crystals can be squashed as well as dried out in vacuum for one week. Other refining approaches consist of: converting oleic acid right into methyl oleate, hydrolyzing the ester after fractionation, and also recrystallizing the complimentary acid with acetone at -40 ~ -45 ° C. Use 12 mL of acetone per 1 g of oleic acid. There is likewise a method of fractional crystallization of the melt of oleic acid, followed by molecular distillation filtration at a stress of 133.3 MPa.

3. Take oil and hydrolyze to obtain blended fat, and also the liquid part acquired by cold pressing is Pure Oleic Acid, and the solid part of saturated fatty acid is removed. Acetone can be used as solvent to acquire pure product.

4. Making use of stearic acid co-production method. In the synthesis of stearic acid, the pressed unsaturated fats are additional frozen as well as pushed, the saturated fatty acids are separated, and afterwards dried out. Or in the prep work of grease, the soapstock is gotten by saponification, acidification, separation and distillation.

Preparation Method of Pure Oleic Acid

(1) Extract Pure Oleic Acid directly from vegetable oil, that is, extract by saponification method, blow steam into the oil under stirring, raise the temperature to 80-100 ℃, and then add lye to hydrolyze the oil. After hydrolysis, mixed fatty acids are obtained, and these are separated by distillation and cooling. This method is labor-intensive, energy consumption, and alkali consumption, and is generally not used.
(2) Using vegetable oil or animal oil as raw material, the Pure Oleic Acid is prepared by normal pressure catalytic hydrolysis method, and the catalyst can be alkylbenzene sulfonic acid. The intermittent medium-pressure catalytic cracking method can also be used, and the catalyst can be selected from zinc oxide, the pressure is 10.13×105~35.46×105Pa, and the temperature is 150~230℃. Continuous, countercurrent, high pressure cracking method can also be used, the pressure is 5-5.2MPa, the temperature is 260℃, and zinc oxide can be used as the catalyst. This method has higher benefits than the previous two, but it is not suitable for oils with high unsaturation and hydroxyl groups. . Using the above three methods, mixed fatty acids can be prepared, and then separated and refined. First, a crude fraction was carried out by distillation, and the distillation was carried out under reduced pressure (0.133×10 3 to 1.07×10 3 Pa). The distillation temperature was maintained not to exceed 260°C. The distilled fatty acids are further rectified using their boiling point difference. Depending on the melting point of various fatty acids, it can be purified by a crystallization method. It can also be purified by solvent extraction.
(3) Artificial synthesis of Pure Oleic Acid. In 1925, oleic acid was synthesized from ethyl acetoacetate. With the development of the petrochemical industry, the synthesis of Pure Oleic Acid has also been developed, and Pure Oleic Acid can be prepared from petroleum olefins.

Company Profile and Corporate Culture

Company Profile:

ZhiShang Chemical is owned by ZhiShang Group is a professional new-type chemicals enterprise combined into research and development, production and sales .

The company’s competitive product is pharmaceutical raw materials and intermediates (especially carbohydrate derivatives Series), In recent years, the company has made a major breakthrough in food and feed additives, plant extraction, industrial chemicals industry .

The company insists on the spirit of “sincere management, strict quality control, customer as god” , get consistent high praise from customers at home and abroad.

Corporate Culture:

OUR MISSION
Help China Chemicals to benefit the happiness of human life
OUR VISSION
Become the most trusted chemical supplier in the world
OUR BUSINESS PHILOSOPHY
Striver – oriented, enrich employees, customer first, deep service, seek development
OUR VALUES
Be prepared for danger in times of peace, forge ahead actively, unity and cooperation, and be brave to fight

About Us

The production base is located in Zhangqiu chemical industry park and Tai’an high-tech chemical industry park. laboratory and workshop in strict accordance with the GMP standard and the product fit national ISO9001 and ISO2000 standards.

“Zhishang” products are exported to Europe, North and South America, the Middle East, Asia Pacific and Africa area, so as to establish a long-term and stable cooperation relationship with customer in the world.

Company Info
  • Business Type: Manufacturer
  • Product Range: Additive , Chemical Auxiliary & Catalyst , Organic Chemicals
  • Products/Service: Organic Intermediate,Inorganic Chemistry, APIs, Dyestuffs And Pigments, Fragrance And Spices, Food Additives
  • Total Employees: 51~100
  • Capital (Million US $): 10000000RMB
  • Year Established: 2016
Production Capacity
  • No. of Production Lines : 8
  • No. of QC Staff : 5 -10 People
  • OEM Services Provided : yes
  • Factory Size (Sq.meters) : 3,000-5,000 square meters
  • Certificate: ISO9001 , CE , GMP , API , MSDS
  • Factory Location : Diao Town Industry Park, Zhangqiu City, Jinan City, Shandong Province, China.

Service

Pre-Sales Service

* Prompt reply and 24 hours online, professional team to provide best price and high quality product.

* Sample testing support.

* Every batch of products will be tested to ensureits quality.

*The packing also can be according the customers` requirment.

*Any inquiries will be replied within 24 hours.

*we provide Commerical Invoice, Packing List, Bill of loading, COA , Health certificate and Origin certificate. If your markets have any special requirements, let us know.

 

After-Sales Service

*The fact of logistics information monitoring.

* Any questions about the product can be consulted at any time.

*Product has any problem can return.

FAQ

Do you accept sample order?

We will make samples before mass production, and after sample approved, we’ll begin mass production. Doing 100% inspection during production, then do random inspection before packing.

 

HOW TO CONFIRM THE PRODUCT QUALITY BEFORE PLACING ORDERS?

You can get free samples for some products,you only need to pay the shipping cost or arrange a courier to us and take the samples. You can send us your product specifications and requests,we will manufacture the products according to your requests.

What’s your MOQ?

Our MOQ is 1kg. But usually we accept less quantity such as 100g on the condition that sample charge is 100% paid.

Do you supply product report?

Yes. We’ll give you product analysis report before shipping.

  Is there a discount?

Different quantity has different discount.

Shipping

1. ≤50kg, Express delivery recommended, usually called as DDU service;

2. ≤500kg, Air shipping recommended, usually called as FOB, CFR, or CIF service;

3. >500kg, sea shipping recommended, usually called as FOB, CFR, or CIF service;

4. For high value products, please select air shipping and express delivery for safe.

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