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Zhishang Chemical

Methyl Methyl Anthranilate CAS 134-20-3

Molecular Formula: C8H9NO2

Formula Weight: 151.16

ZSpharmac: Methyl Methyl Anthranilate Supplement

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Product Name: Methyl Methyl Anthranilate
CAS No: 134-20-3
Purity: 99%

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Basic Info

Product Name:Methyl Methyl Anthranilate
Other Names:Methyl Anthranilate
Place of Origin:Shandong, China
Brand Name:ZSpharmac
Type:Cosmetic Raw Materials
Appearance:Clear Yellow-Brown Liquid
EINECS No.:205-132-4
Storage:Keep in Dark Place,Inert Atmosphere,Room Temperature
Provide:Methyl Methyl Anthranilate MSDS;
Methyl Methyl Anthranilate COA

What is Methyl Methyl Anthranilate?

Methyl Methyl Anthranilate is both an ester as well as a fragrant main amine, so it has the twin residential or commercial properties of an ester and an amine. When it is included in the essence containing other aldehydes, it can undertake condensation response with aldehydes to create Schiff bases (Sch near Base) with more secure residential or commercial properties and more powerful aroma.

A lot of the Schiff bases have a dark color, yet some are light orange and have a strong scent, which is a great agent in the essence. As a result of their solid fruity and also floral scents, these compounds have been widely used in day-to-day and also edible flavors.Methyl Methyl Anthranilate is just one of the foundation products of the scent industry, from which around 60 fragrances can be prepared; Menthyl anthranilate acquired by transesterification with menthol is an effective sun block.

Methyl Methyl Anthranilate Properties:

Melting point 24 °C (lit.)
Boiling point 256 °C (lit.)
density 1.168 g/mL at 25 °C (lit.)
vapor pressure 1 mm Hg ( 20 °C)
refractive index n20/D 1.582(lit.)
Fp 220 °F
storage temp. Keep in dark place,Inert atmosphere,Room temperature
solubility alcohol: freely soluble(lit.)
pkapK1:2.23(+1) (25°C)
form Liquid
color Clear yellow-brown
Odorgrape odor
PH7.5-8 (H2O, 20℃)Aqueous solution
explosive limit1.4-7.8%(V)
Water Solubility slightly soluble


Methyl Methyl Anthranilate Uses

  1. Methyl Anthranilate is just one of the backbone products of the scent industry and also is widely utilized in daily tastes as well as food flavors. In edible flavors, it is the main flavor of grape taste, and can also be used in various fruit flavors such as berries, melon, honey, citrus, lemon, strawberry as well as pineapple. Around 60 sort of fragrances can likewise be prepared from Methyl Anthranilate. For instance, other Methyl Anthranilate prepared by transesterification of methyl anthranilate is one of the frequently used basic materials for fragrance, which is extensively made use of and also has high value; it is combined with some aldehydes. Condensation response occurs to generate Schiff base with even more secure buildings and also more powerful scent, which is a great fixative essentially.
  2. Methyl Methyl Anthranilate is a food flavor allowed by my country’s “Hygienic Specifications for using Food Additives”, as well as is used to prepare watermelon, citrus, grape, strawberry as well as various other fruit-type edible flavors and also wine flavors. 2200mg/kg in eating gum; 56mg/kg in sweet; 23mg/kg in puddings; 21mg/kg in cool drinks; 20mg/kg in baked goods; 16rng/kg in sodas; 0.2 mg/kg in alcohol.
  3. Methyl Methyl Anthranilate can be used as an intermediate for pesticides and saccharin. Methyl anthranilate has a pleasant scent of tower flower, and also has a grape-like fragrance when diluted. It is utilized in the blending of cheap artificial flower oils, and additionally in soap fragrance or grape significance. my country’s GB2760-86 stipulates that it is enabled to make use of edible spices. It is mostly used to prepare tastes such as grape, citrus, loganberry, strawberry and also watermelon. Anthranilates can react with aldehydes to develop important soap-based flavors, such as hydroxyaromatic aldehyde and methyl anthranilate. The complying with scents were gotten. This spice has actually been readily available in China under the trade name Aurantiol. The oral LD50 of rats is 2910mg/kg and that of mice is 3900mg/kg.

Preparation Method of Methyl Methyl Anthranilate

Other Applications of Methyl Methyl Anthranilate

Bromhexine hydrochloride is a synthetic drug obtained by structural modification of Vasicine, and its hydrochloride is commonly used. It is a white to off-white crystalline powder, easily soluble in methanol and ethanol, and slightly soluble in water. Mainly used for the mucus-producing cells of the trachea and bronchial mucosal glands to secrete low-viscosity small-molecule mucins, thereby restoring the rheological properties of tracheal and bronchial secretion to normal, reducing viscous phlegm and diluting sputum. , easy to pull out.

CN201310540763.0 discloses a method for synthesizing and producing bromhexine hydrochloride. The method takes Methyl Methyl Anthranilate as the starting material, synthesizes 3,5-dibromo Methyl Methyl Anthranilate through the bromination reaction of bromine and hydrochloric acid, and then uses potassium borohydride, Ethanol is used as the raw material for reduction reaction to synthesize 3,5-dibromo-o-aminophenol, and then condensed with N-methylcyclohexylamine to form bromhexine, and hydrochloric acid is added to form a salt to synthesize the crude product of bromhexine hydrochloride, and finally recrystallized with ethanol to obtain Bromhexine hydrochloride. The synthetic route adopted by the invention is short, the operation is simple and convenient, the starting materials are easily obtained, the intermediate performance is stable, the product yield is high, the production cost is low, and is suitable for industrial scale production.

Company Profile and Corporate Culture

Company Profile:

ZhiShang Chemical is owned by ZhiShang Group is a professional new-type chemicals enterprise combined into research and development, production and sales .

The company’s competitive product is pharmaceutical raw materials and intermediates (especially carbohydrate derivatives Series), In recent years, the company has made a major breakthrough in food and feed additives, plant extraction, industrial chemicals industry .

The company insists on the spirit of “sincere management, strict quality control, customer as god” , get consistent high praise from customers at home and abroad.

Corporate Culture:

Help China Chemicals to benefit the happiness of human life
Become the most trusted chemical supplier in the world
Striver – oriented, enrich employees, customer first, deep service, seek development
Be prepared for danger in times of peace, forge ahead actively, unity and cooperation, and be brave to fight

About Us

The production base is located in Zhangqiu chemical industry park and Tai’an high-tech chemical industry park. laboratory and workshop in strict accordance with the GMP standard and the product fit national ISO9001 and ISO2000 standards.

“Zhishang” products are exported to Europe, North and South America, the Middle East, Asia Pacific and Africa area, so as to establish a long-term and stable cooperation relationship with customer in the world.

Company Info
  • Business Type: Manufacturer
  • Product Range: Additive , Chemical Auxiliary & Catalyst , Organic Chemicals
  • Products/Service: Organic Intermediate,Inorganic Chemistry, APIs, Dyestuffs And Pigments, Fragrance And Spices, Food Additives
  • Total Employees: 51~100
  • Capital (Million US $): 10000000RMB
  • Year Established: 2016
Production Capacity
  • No. of Production Lines : 8
  • No. of QC Staff : 5 -10 People
  • OEM Services Provided : yes
  • Factory Size (Sq.meters) : 3,000-5,000 square meters
  • Certificate: ISO9001 , CE , GMP , API , MSDS
  • Factory Location : Diao Town Industry Park, Zhangqiu City, Jinan City, Shandong Province, China.


Pre-Sales Service

* Prompt reply and 24 hours online, professional team to provide best price and high quality product.

* Sample testing support.

* Every batch of products will be tested to ensureits quality.

*The packing also can be according the customers` requirment.

*Any inquiries will be replied within 24 hours.

*we provide Commerical Invoice, Packing List, Bill of loading, COA , Health certificate and Origin certificate. If your markets have any special requirements, let us know.


After-Sales Service

*The fact of logistics information monitoring.

* Any questions about the product can be consulted at any time.

*Product has any problem can return.


Do you accept sample order?

We will make samples before mass production, and after sample approved, we’ll begin mass production. Doing 100% inspection during production, then do random inspection before packing.



You can get free samples for some products,you only need to pay the shipping cost or arrange a courier to us and take the samples. You can send us your product specifications and requests,we will manufacture the products according to your requests.

What’s your MOQ?

Our MOQ is 1kg. But usually we accept less quantity such as 100g on the condition that sample charge is 100% paid.

Do you supply product report?

Yes. We’ll give you product analysis report before shipping.

  Is there a discount?

Different quantity has different discount.


1. ≤50kg, Express delivery recommended, usually called as DDU service;

2. ≤500kg, Air shipping recommended, usually called as FOB, CFR, or CIF service;

3. >500kg, sea shipping recommended, usually called as FOB, CFR, or CIF service;

4. For high value products, please select air shipping and express delivery for safe.

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