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Heptaldehyde CAS 111-71-7

Molecular Formula: C7H14O

Formula Weight: 114.19

ZSpharmac: Heptaldehyde Raw Material Supplier

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Product Name: Heptaldehyde
CAS No: 111-71-7
Purity: 99%

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Basic Info

Product Name:Heptaldehyde
Other Names:Heptanal
CAS:111-71-7
Place of Origin:Shandong, China
Brand Name:ZSpharmac
Type:Cosmetic Raw Materials
Appearance:White to Light Yellow Beige Powder
EINECS No.:203-898-4
Storage:Flammables Area
Provide:Heptaldehyde MSDS;
Heptaldehyde COA

What is Heptaldehyde?

N-Heptanal, also called heptanal, is miscible with ethanol and ether, soluble in 60% ethanol, and a little soluble in water. It can be reduced to n-heptyl alcohol and oxidized to n-heptanoic acid, which exists in castor oil. N-Heptanal can be used as a basic material for organic synthesis, such as the synthesis of δ-laurolactone. Lactone is a vital organic substance and intermediate and has broad application and advancement potential customers in the fields of scent and pharmaceutical synthesis.

For instance, γ- and δ-lactones have been utilized in high-end cosmetics, food and tobacco industries, and due to the fact that lactones are the main components of all-natural butter flavor, and all-natural butter consists of a large amount of pet fat, excessive inhalation can quickly cause cardiovascular disease. Some established countries utilize vegetable oil to add lotion flavor as margarine for usage in the food industry, and the flavor is virtually the same as all-natural cream. Using this brand-new top notch lotion flavor can decrease the amount of cream in food and play a vital role in securing individuals’s health.

Heptaldehyde Property

Melting point 

-43 °C (lit.)

Boiling point 

153 °C (lit.)

density 

0.817 g/mL at 25 °C (lit.)

vapor pressure 

3 hPa (20 °C)

refractive index 

n20/D 1.413(lit.)

Fp 

95 °F

storage temp. 

Flammables area

solubility 

1.25g/l insoluble

form 

Powder, Crystals or Chunks

color 

White to light yellow-beige

Odor

at 1.00 % in dipropylene glycol. fresh aldehydic fatty green herbal wine-lee ozone

Odor Type

green

Odor Threshold

0.00018ppm

explosive limit

1.1-5.2%(V)

Water Solubility 

insoluble

 

Heptaldehyde Uses

1. Due to the fact that it originates from castor oil or among the bosom items of ricinoleic acid methyl ester, Heptaldehyde is mainly made use of as a resources for the synthesis of perfume-α-amylcinnamic aldehyde and corresponding homologous derivatives. The dosage for various types of edible tastes is 1.2 ~ 4.9 mg/kg. Utilized as soap taste, detergent taste, perfume flavor, lotion flavor, and so on

2. Heptaldehyde is a vital resources for artificial flavors and is also a basic material for pharmaceuticals, organic synthesis and rubber products.

Heptaldehyde Application

Heptaldehyde can be made use of to prepare orange essence and climbed essence, and can on top of that be made use of to prepare n-heptanoic acid, which is made use of as a resources for all-natural synthesis. Situations of its applications are as complies with:

1. Preparation job of 2-heptylcyclopentanone.
Under the work of sodium hydroxide energizer, cyclopentanone, n-heptanal and stage transfer energizer respond at 50 ~ 80 ℃ for 8 ~ 10 hours, adjust the pH well worth to 6 ~ 7, include toluene, and mix at 100 ~ 120 ℃ Till bid farewell to water is created, the ended up product is absolutely obtained utilizing cleansing and drying. The molar proportion of cyclopentanone and Heptaldehyde is (1 ~ 1.3):1. Choosing β-cyclodextrin as a phase transfer energizer can raise the response price and promote cross-condensation.

2. Preparation job of δ-laurolactone.
Include the sticking to jobs:
( 1) Condensation and dehydration: Contain 0.5% to 20% mass section of salt hydroxide service, cyclopentanone and stage transfer energizer right into a three-necked flask, raise the temperature to 10 to 50 ° C, contain Heptaldehyde dropwise, and surface area dripping in 1 to 4 hours. (The molar percentage of cyclopentanone to n-heptaldehyde is 1:1 to 5:1). Given that the job of the condensation response in between aldehydes and aldehydes is above the task of the condensation responses in between aldehydes and ketones, an extra of ketones is asked for to stop excessive side responses.

After that respond at a consistent temperature level of 10 to 50 ° C for 1 to 3 hours, fantastic, and lower the impacts of with acetic acid to make the mix pH=5 to 6. Enable stand and different right into layers, remove the fluid layer with an extractant, integrate the organic stages, cleaning with 5% NaHCO3 and saturated NaCl fluid treatment, transfer to a gadget with a water separator, comfortable and completely dry. After cooling off, neat, completely dry with anhydrous Na2SO4, evaporate the extractant under normal tension of 105, lower the anxiety and anxiousness to 350 ~ 450 for purification, and build up the 2-heptenecyclopentanone part at 90-100 ° C/350 ~ 450 Pa.

( 2) Hydrogenation: Consist Of 2-heptenecyclopentanone to the activator in N2 ambience, after that consist of ion exchange resin-supported palladium energizer and solvent, and existing H2 at typical tension and 10 to 50 ° C till the response no longer absorbs Hydrogen stops. Washing the ion exchange material kept palladium stimulant with solvent. Revolving vaporize to eliminate the solvent in the feedback, reduced the anxiety to 250Pa-270Pa for filtering system, and gather the part 2-heptylcyclopentanone at 75-85 ° C/250 -270 Pa.

( 3) Oxidation: Include methanol as the solvent to the three-necked flask, afterwards consist of 2-heptylcyclopentanone and acid accelerator, mix and decrease the oxidant at 20 to 60 ° C. Consistently made use of oxidants are hydrogen peroxide and oxygen, which are significantly exceptionally easy to guard the setup. However, the reaction selectivity and conversion cost of using oxygen as the oxidant are generally decreased, so using hydrogen peroxide is especially essential. After the dropwise improvement, preserve the temperature level degree constant at 20-60 ° C, interest to track the reaction to verdict, include water, continue blending, tidy with water, combat with 5% NaHCO3, clean the liquid layer with toluene, integrate the all-natural stages, and come down to eliminate the toluene in the natural layer under normal tension of 105Pa., manage the temperature degree not to go beyond 60 ° C, and the residue is raw δ-laurolactone.

( 4) Refining of the raw product: Condense the above crude thing making use of a molecular filtration tool, take care of the temperature degree to 120-130 ° C and the pressure to 300Pa, and gather the fit to be linked product, which is δ-laurolactone.

Heptaldehyde Preparation

Step 1: Synthesis of benzimidazole: Consist of 0.1 mol o-phenylenediamine and 0.15 mol formic acid right into a 100 mL round-bottomed flask, warm to reflux at 90 ° C for 2 h, cool, and take advantage of 10% NaO with mixing: The H service was gotten used to rather alkaline. After suction filtering system and water recrystallization, white half-cracked crystals were gotten. The return was 88%, mp 171 ~ 173 ℃.

Task 2: Synthesis of 1,3-dimethylbenzimidazole salt: 0.02 mol of benzimidazole was liquified in an ethanol option (8 mL) having 0.02 mol of salt ethoxide, and 0.05 mol was added Methyl iodide and 20 mL benzene were reacted at reflux temperature level for 18 hours, cooled, filteringed system, and the strong was recrystallized with absolute ethanol or acetone to get 4.39 g of white strong, return 80%, mp 201 ~ 202 ° C. Action 3: Synthesis of 1,3-dimethyl-2-hexylbenzimidazolidine: Under N2 gas protection, 0.02 mol 1,3-dimethyl-2-H benzimidazole salt was added to 0 in collections. 04 mol of Grig nard reagent in tetrahydrofuran alternative, mix for 15 hours after enhancement, evaporate the solvent, significance the residue with cyclohexane (40 mL × 3), totally dry over magnesium sulfate, and evaporate the cyclohexane to acquire anemic Oily product, bp 95 ~ 96 ℃/ 2. 50 kPa.

Idea 4: Synthesis of n-heptaldehyde: Under N2 gas defense, add 0.02 mol 1,3-dimethylbenzimidazole salt in sets to the tetrahydrofuran remedy of 0.04 mol Grig nard reagent in a warm water bathroom, Mix the feedback in a comfy water restroom at 50 ~ 70 ° C for 16 ~ 18 hours. Include 5% hydrochloric acid liquid service to adjust the pH value to 3 ~ 4, continue mixing in an enjoyable water restroom for half an hour, vaporize the solvent, and extract with ether. The essence is cleansed with 5% NaHCO3 solution and water especially, dried with anhydrous MgSO4 overnight, and evaporated. Diethyl ether is distilled to gather the section at 151 ~ 152 ° C, which is Heptaldehyde, with a return of 65%.

About Products:
If you need the cosmetic raw material Heptaldehyde, please contact our service staff directly, we will provide you with high-quality products at the best price.
Our company, as an experienced Heptaldehyde manufacturer and supplier, ZSpharmac will provide Heptaldehyde raw materials to customers around the world for a long time.
Over the years, the company has adhered to the spirit of “integrity management, strict quality control, and customer first” and has won unanimous praise from customers at home and abroad.

Company Profile and Corporate Culture

Company Profile:

ZhiShang Chemical is owned by ZhiShang Group is a professional new-type chemicals enterprise combined into research and development, production and sales .

The company’s competitive product is pharmaceutical raw materials and intermediates (especially carbohydrate derivatives Series), In recent years, the company has made a major breakthrough in food and feed additives, plant extraction, industrial chemicals industry .

The company insists on the spirit of “sincere management, strict quality control, customer as god” , get consistent high praise from customers at home and abroad.

Corporate Culture:

OUR MISSION
Help China Chemicals to benefit the happiness of human life
OUR VISSION
Become the most trusted chemical supplier in the world
OUR BUSINESS PHILOSOPHY
Striver – oriented, enrich employees, customer first, deep service, seek development
OUR VALUES
Be prepared for danger in times of peace, forge ahead actively, unity and cooperation, and be brave to fight

About Us

The production base is located in Zhangqiu chemical industry park and Tai’an high-tech chemical industry park. laboratory and workshop in strict accordance with the GMP standard and the product fit national ISO9001 and ISO2000 standards.

“Zhishang” products are exported to Europe, North and South America, the Middle East, Asia Pacific and Africa area, so as to establish a long-term and stable cooperation relationship with customer in the world.

Company Info
  • Business Type: Manufacturer
  • Product Range: Cosmetic raw materials
  • Products/Service:Cosmetic raw materials (flavors and fragrances,antioxidant products, moisturizing and hydrating, whitening agents, cosmetic additives)
  • Total Employees: 51~100
  • Capital (Million US $): 10000000RMB
  • Year Established: 2016
Production Capacity
  • No. of Production Lines : 8
  • No. of QC Staff : 5 -10 People
  • OEM Services Provided : yes
  • Factory Size (Sq.meters) : 3,000-5,000 square meters
  • Certificate: ISO9001 , CE , GMP , API , MSDS
  • Factory Location : Diao Town Industry Park, Zhangqiu City, Jinan City, Shandong Province, China.

Service

Pre-Sales Service

* Prompt reply and 24 hours online, professional team to provide best price and high quality product.

* Sample testing support.

* Every batch of products will be tested to ensureits quality.

*The packing also can be according the customers` requirment.

*Any inquiries will be replied within 24 hours.

*we provide Commerical Invoice, Packing List, Bill of loading, COA , Health certificate and Origin certificate. If your markets have any special requirements, let us know.

 

After-Sales Service

*The fact of logistics information monitoring.

* Any questions about the product can be consulted at any time.

*Product has any problem can return.

FAQ

Do you accept sample order?

We will make samples before mass production, and after sample approved, we’ll begin mass production. Doing 100% inspection during production, then do random inspection before packing.

 

HOW TO CONFIRM THE PRODUCT QUALITY BEFORE PLACING ORDERS?

You can get free samples for some products,you only need to pay the shipping cost or arrange a courier to us and take the samples. You can send us your product specifications and requests,we will manufacture the products according to your requests.

What’s your MOQ?

Our MOQ is 1kg. But usually we accept less quantity such as 100g on the condition that sample charge is 100% paid.

Do you supply product report?

Yes. We’ll give you product analysis report before shipping.

  Is there a discount?

Different quantity has different discount.

Shipping

1. ≤50kg, Express delivery recommended, usually called as DDU service;

2. ≤500kg, Air shipping recommended, usually called as FOB, CFR, or CIF service;

3. >500kg, sea shipping recommended, usually called as FOB, CFR, or CIF service;

4. For high value products, please select air shipping and express delivery for safe.

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