Zhishang Chemical

Welcome to Zhishang Chemical      +86-176 5311 3209     Simon@sdzschem.com

Zhishang Chemical

Geranyl Acetate CAS 105-87-3

Molecular Formula: C12H20O2

Formula Weight: 196.29

ZSpharmac: Geranyl Acetate Supplement

Share on facebook
Facebook
Share on twitter
Twitter
Share on linkedin
LinkedIn
Share on pinterest
Pinterest
Share on whatsapp
WhatsApp
Share on email
Email
Product Name: Geranyl Acetate
CAS No: 105-87-3
Purity: 99%

Basic Info

Product Name:Geranyl Acetate
Other Names:Geranyl Acetate, 70%
CAS:105-87-3
Place of Origin:Shandong, China
Brand Name:ZSpharmac
Type:Daily Chemical Raw Materials
Appearance:Colorless to Pale Yellow Transparent Liquid
EINECS No.:203-341-5
Storage:2-8°C
Provide:Geranyl Acetate MSDS;
Geranyl Acetate COA

What is Geranyl Acetate?

Geranyl acetate, also known as geranyl acetate or geranyl acetate,
Natural geranyl acetate exists in natural aromatic oils such as camphor oil, ylang ylang oil, neroli oil, orange leaf oil, citronella oil, coriander seed oil, lemongrass oil, etc., and can be extracted from it, or after extracting geraniol. Synthesize again.

Geranyl Acetate Properties:

Melting point 25°C
Boiling point 236-242 °C(lit.)
density 0.916 g/mL at 25 °C
vapor density 6.8 (vs air)
vapor pressure 0.07 mm Hg ( 20 °C)
refractive index n20/D 1.462
FEMA 2509 | GERANYL ACETATE
Fp 220 °F
storage temp. 2-8°C
solubility Chloroform (Slightly), Ethyl Acetate (Slightly), Methanol (Slightly)
form neat
Specific Gravity0.916
color Colourless
Water Solubility <0.1 g/100 mL at 20 ºC

 

Geranyl Acetate Uses

  1. Geranyl Acetate is defined as an allowed flavoring. Mostly used to prepare flavors such as apples, pears and berries.
  2. Geranyl Acetate is made use of to formulate floral fragrances such as rose.
  3. Geranyl Acetate is functional and also offered in both floral as well as fruity formulas. It is commonly utilized in various climbed essences to sweeten and also change. It is intensified with lily of the valley, vanilla, ylang-ylang, asian, as well as also grass-flavored as well as other tastes, as well as has a harmonious sweetening result.
  4. Geranyl Acetate is pleasant as well as tranquil, with the fragrance of rose, bergamot as well as lavender. It is the raw material needed for all increased flavor flavors and also is one of the most important range of geranyl esters.

Preparation of Geranyl Acetate

report one,
Take 14.48g of acetic acid and 30.84g of geraniol, mix them uniformly and add them into a three-necked flask, add 5g of acidic functionalized ionic liquid catalyst, heat under reflux and stir, use a water separator to separate water, react at 110 °C for 2 hours, and extract with ether after cooling , the raffinate is the recovered catalyst, the ether is recovered under reduced pressure, and the geranyl acetate is obtained by distillation.

report two,
Catalyst preparation method: Weigh 4.0g of titanium sulfate and 2.0g of ethyl orthosilicate. Under the condition of ultrasonic assistance, the ultrasonic frequency is 40KHZ, and the co-co-polymer of Ti(OH)4 and Si(OH)4 is prepared by sol-gel method. Precipitation, then impregnated with 0.5mol/L sulfuric acid for 5 hours, dried at 120°C, and calcined at 550°C for 4 hours to obtain SO42-/TiO2-SiO2 solid super acid.

3.08g of natural geraniol (content 93.8%), 0.05g of SO42-/TiO2-SiO2 solid superacid and 4.04g of acetic anhydride were placed in a round-bottomed flask, heated in an oil bath under electromagnetic stirring and heated to 50°C to maintain this The temperature is 1 hour, connected to the vacuum distillation equipment of the water pump, the vacuum degree is 50mmHg, and the temperature is slowly raised to 90 ℃ to distill off the water, acetic acid and the remaining acetic anhydride generated by the reaction. Use a moist pH test paper to check whether the acetic acid is removed, and the distillation is completed. After cooling to room temperature, suction filtration, dry the solid, wash the solid with petroleum ether, distill the filtrate with a rotary evaporator to recover the petroleum ether, remove the petroleum ether by natural volatilization of the solid, put it in an oven, dry it, and use it for the next reaction. Under the condition of vacuum degree of 50mmHg and temperature of 90℃, 4.35g of geranyl acetate was obtained by distillation (the content of geranyl acetate was 94.5%, and the content of isomerized by-products was 0.2%).

Application of Geranyl Acetate

CN03150555.4 discloses a synthesis method of geraniolgeraniol.
The method is as follows: using geranyl acetate as a raw material, firstly in a solvent dichloromethane, the (E)-methyl group of geranyl acetate is selectively oxidized by using selenium dioxide-tert-butyl hydroperoxide binary oxidant, A mixed oxidation product of trans (E formula) allylic carbonylation and hydroxylation is obtained; then, sodium borohydride is used for reduction in methanol to obtain a single oxidation product, geranyl 8-hydroxyacetate. The trans-8-hydroxyacetate geranyl ester is reacted with phosphorus tribromide in anhydrous ether in the presence of pyridine to obtain the trans-8-bromoacetate geranyl ester. Then, in N,N-dimethylformamide, in the presence of potassium tert-butoxide, geranyl sulfone and trans-8-bromoacetate geraniol are condensed to obtain 9-sulfonylgeranylgeraniol. 9-sulfonylgeranylgeraniol, using lithium in methylamine to reductively remove the sulfone group to obtain the target product geranylgeraniol. The invention is a synthetic method with cheap and easy-to-obtain reagents and mild reaction conditions.

Geranyl Acetate Environmental Fate/Exposure Summary

The production and use of geranyl acetate as a flavoring and scent may lead to its release into the atmosphere with various waste streams. Geranyl acetate is a component of vital oils. If launched into the air, the estimated vapor pressure at 25 ° C is 3.3X10-2 mm Hg, which shows that geranyl acetate will just exist in the environment as a vapor. Gas-phase geranyl acetate is degraded in the environment by response with photochemically produced hydroxyl radicals; the half-life of this reaction in air is approximated to be 2 hrs. Geranyl acetate does include a chromophore that soaks up at wavelengths > 290 nm as well as hence might be vulnerable to guide photolysis by sunlight. If launched right into soil, geranyl acetate is anticipated to be somewhat mobile based on an estimated Koc of 3,700. Based on the estimated Henry’s Legislation constant of 2.4X10-3 atm-cu m/mole, volatilization from moist soil surface areas is expected to be an important destiny process. However, adsorption to dirt is expected to undermine volatilization. No biodegradation information. If launched to the approximated Koc, geranyl acetate is anticipated to adsorb into put on hold solids and also debris.

Based on the approximated Henry’s Legislation constant for this compound, volatilization from the water surface is expected to be an important destiny process. The estimated volatilization half-lives for the model river as well as version lake are 7.4 hrs and also 6.5 days, respectively. However, unpredictable columns at the water surface are expected to be damaged by adsorption to suspended solids as well as debris in the water. If adsorption is thought about, the estimated volatilization half-life for the design fish pond is one month. The approximated BCF is 260, indicating a high capacity for bioconcentration in aquatic organisms. Hydrolysis is anticipated based on estimated second hydrolysis half-lives of 231 and 23 days at pH values of 7 and 8, respectively. Job-related exposure to geranyl acetate may occur via inhalation and dermal exposure to the substance in workplaces where geranyl acetate is generated or made use of. Surveillance information recommend that the basic population may be subjected to geranyl acetate via inhalation, ingestion of food, and also facial contact with this compound and various other consumer products consisting of geranyl acetate.

Company Profile and Corporate Culture

Company Profile:

ZhiShang Chemical is owned by ZhiShang Group is a professional new-type chemicals enterprise combined into research and development, production and sales .

The company’s competitive product is pharmaceutical raw materials and intermediates (especially carbohydrate derivatives Series), In recent years, the company has made a major breakthrough in food and feed additives, plant extraction, industrial chemicals industry .

The company insists on the spirit of “sincere management, strict quality control, customer as god” , get consistent high praise from customers at home and abroad.

Corporate Culture:

OUR MISSION
Help China Chemicals to benefit the happiness of human life
OUR VISSION
Become the most trusted chemical supplier in the world
OUR BUSINESS PHILOSOPHY
Striver – oriented, enrich employees, customer first, deep service, seek development
OUR VALUES
Be prepared for danger in times of peace, forge ahead actively, unity and cooperation, and be brave to fight

About Us

The production base is located in Zhangqiu chemical industry park and Tai’an high-tech chemical industry park. laboratory and workshop in strict accordance with the GMP standard and the product fit national ISO9001 and ISO2000 standards.

“Zhishang” products are exported to Europe, North and South America, the Middle East, Asia Pacific and Africa area, so as to establish a long-term and stable cooperation relationship with customer in the world.

Company Info
  • Business Type: Manufacturer
  • Product Range: Additive , Chemical Auxiliary & Catalyst , Organic Chemicals
  • Products/Service: Organic Intermediate,Inorganic Chemistry, APIs, Dyestuffs And Pigments, Fragrance And Spices, Food Additives
  • Total Employees: 51~100
  • Capital (Million US $): 10000000RMB
  • Year Established: 2016
Production Capacity
  • No. of Production Lines : 8
  • No. of QC Staff : 5 -10 People
  • OEM Services Provided : yes
  • Factory Size (Sq.meters) : 3,000-5,000 square meters
  • Certificate: ISO9001 , CE , GMP , API , MSDS
  • Factory Location : Diao Town Industry Park, Zhangqiu City, Jinan City, Shandong Province, China.

Service

Pre-Sales Service

* Prompt reply and 24 hours online, professional team to provide best price and high quality product.

* Sample testing support.

* Every batch of products will be tested to ensureits quality.

*The packing also can be according the customers` requirment.

*Any inquiries will be replied within 24 hours.

*we provide Commerical Invoice, Packing List, Bill of loading, COA , Health certificate and Origin certificate. If your markets have any special requirements, let us know.

 

After-Sales Service

*The fact of logistics information monitoring.

* Any questions about the product can be consulted at any time.

*Product has any problem can return.

FAQ

Do you accept sample order?

We will make samples before mass production, and after sample approved, we’ll begin mass production. Doing 100% inspection during production, then do random inspection before packing.

 

HOW TO CONFIRM THE PRODUCT QUALITY BEFORE PLACING ORDERS?

You can get free samples for some products,you only need to pay the shipping cost or arrange a courier to us and take the samples. You can send us your product specifications and requests,we will manufacture the products according to your requests.

What’s your MOQ?

Our MOQ is 1kg. But usually we accept less quantity such as 100g on the condition that sample charge is 100% paid.

Do you supply product report?

Yes. We’ll give you product analysis report before shipping.

  Is there a discount?

Different quantity has different discount.

Shipping

1. ≤50kg, Express delivery recommended, usually called as DDU service;

2. ≤500kg, Air shipping recommended, usually called as FOB, CFR, or CIF service;

3. >500kg, sea shipping recommended, usually called as FOB, CFR, or CIF service;

4. For high value products, please select air shipping and express delivery for safe.

Get Geranyl Acetate Quotation