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Butylhydroxytoluene CAS 128-37-0

Molecular Formula: C15H24O

Formula Weight: 220.35

ZSpharmac: Butylhydroxytoluene Supplier

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Product Name: Butylhydroxytoluene
CAS No: 128-37-0
Purity: 99%

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Basic Info

Product Name:Butylhydroxytoluene
Other Names:Butylated Hydroxytoluene
CAS:128-37-0
Place of Origin:Shandong, China
Brand Name:ZSpharmac
Type:Cosmetic Raw Materials
Appearance:White Crystals
EINECS No.:204-881-4
Storage:2-8°C
Provide:Butylhydroxytoluene MSDS;
Butylhydroxytoluene COA

What is Butylhydroxytoluene?

Ethanolamine EA is the most essential item among amino alcohols, including monoethanolamine MEA, Diethanolamine SigmaDEA as well as triethanolamine TEA. Ethanolamine is an important organic intermediate, extensively utilized in surfactants, artificial detergents, petroleum additives, artificial resins as well as rubber plasticizers, accelerators, vulcanizing agents and lathering representatives, along with gas filtration, liquid antifreeze, Printing as well as dyeing, medication, pesticide, building and construction, army and also various other areas. Many downstream items of ethanolamine are essential great chemical intermediates, and also they are additionally one of the most sought-after chemical items in our nation. Consequently, the application and also growth of ethanolamine has been enhanced to meet the requirements of domestic great chemicals on the one hand, as well as advertise the quick growth of the ethanolamine market on the other hand.

Diethanolamine Sigma, additionally referred to as bishydroxyethylamine, 2,2′-iminobisethanol, is a white crystal or anemic liquid with solid hygroscopicity. It is easily soluble in water, methanol, ethanol, acetone and also benzene, as well as its solubility in benzene (g/100g) at 25 ° C is 4.2 as well as 0.8 in ether. Its usages are: gas detoxifying agent, which can soak up acid gases in the gas, such as carbon dioxide, hydrogen sulfide, sulfur dioxide, and so on. The “Benfield” option used in the artificial ammonia market is generally made up of this item; it is additionally utilized as an emulsifier., lubricating substances, shampoos, thickeners, etc; natural synthesis intermediates for the production of detergent resources, preservatives and day-to-day chemicals (such as surfactants); synthesis of morpholine.

Butylhydroxytoluene Property

Melting point 28 °C (lit.)
Boiling point 217 °C/150 mmHg (lit.)
density 1.097 g/mL at 25 °C (lit.)
vapor density 3.6 (vs air)
vapor pressure <0.98 atm ( 100 °C)
refractive index n20/D 1.477(lit.)
Fp 280 °F
storage temp. 2-8°C
solubility H2O: 1 M at 20 °C, clear, colorless
form Viscous Liquid or Low Melting Solid
color APHA: ≤15
Specific Gravity1.09
OdorMild ammoniacal; faint, fishy; characteristic.
PH11.0-12.0 (25℃, 1M in H2O)
pka8.88(at 25℃)
explosive limit2.1-10.6%(V)
Water Solubility MISCIBLE

 

Butylhydroxytoluene Uses

  1. Butylhydroxytoluene is an oil-soluble antioxidant completely made use of in your house and additionally abroad. Although it is exceptionally unsafe, it has solid antioxidant capacity, extraordinary warm resistance in addition to in addition security and also protection. It has neither certain scent neither color reaction with steel ions, as well as its expense is lowered, simply 1/5 ~ 1/ of that of BHA. 8. It is still taken advantage of as the significant anti-oxidant in our country. It is generally made use of in addition to BHA, and also citric acid or various other all-natural acids are taken advantage of as synergists. Our country states that it can be made use of for edible oil, fried food, biscuits, instant noodles, quick-cooked rice, tinned nuts, dried out fish items in addition to likewise recovered meat products, with a maximum use of 0.2 g/kg. This thing moreover has a certain anti-bacterial outcome, nevertheless weak than BHA.
  2. Butylhydroxytoluene can be used as a feed anti-oxidant to secure vitamins in feed as well as additionally protect versus oxidative loss of fat as well as additionally healthy protein. Furthermore has certain anti-bacterial effect. The optimal dosage is 150g/t. BHT is an oil-soluble antioxidant commonly used in your home in addition to abroad. Although it is really unsafe, it has strong anti-oxidation capability, great cozy resistance along with furthermore security. It has neither particular odor neither shade response with steel ions, as well as likewise its rate is reduced, just 1/8 -1/ 3 of BHA. 5. It is still made use of as the major antioxidant in our nation. It is generally made use of incorporated with BHA, and likewise citric acid or other all-natural acids are used as synergists.
  3. Butylhydroxytoluene is made use of as a general-purpose phenolic anti-oxidant. Generally utilized in polymer products, oil products as well as food handling markets. This thing is a frequently made use of rubber anti-oxidant. It has a specific safety outcome on warm in addition to additionally oxygen aging, as well as furthermore can similarly impede copper damage. It has no anti-ozone ability when taken advantage of alone, nonetheless it can secure vulcanized rubber from different environment problem aspects when utilized together with anti-ozone reps in addition to waxes. It can similarly be utilized as a gelling avoidance in SBR. The essential dosage in rubber is 0.5-3 aspects. When the dose is boosted to 3-5 components, it will not spray frost. This item can additionally be utilized as a stabilizer in the therapy along with storage area of artificial rubber, and likewise moreover can be taken advantage of for rubber kinds such as styrene-butadiene rubber, butadiene rubber, ethylene-propylene rubber, in addition to neoprene rubber. Antioxidant 264 is an efficient anti-oxidant in some polymer things. This product is an effective stabilizer in polyethylene, polyvinyl chloride (0.01-0.1%) together with polyvinyl ether. Antioxidant 264 is a fantastic antioxidant additive for various oil points. Outstanding oil solubility. This product can furthermore be used as an anti-oxidant in the food dealing with market, in addition to it can be utilized in foods with a bargain of fat. The quantity used in oil, butter, dried out fish as well as shellfish items, salted fish along with likewise shellfish products, icy whale meat, and more is less than 0.2 g/kg, together with in a similar way less than 0.75 g/kg in consuming periodontal cells. Utilizing this point consists of dipping method, straight mixing strategy, blending method after liquifying in ethanol in addition to sprinkling strategy, and a lot more. The U.S.A., Japan along with the European Location all utilize this item as an authorized feed additive. The European Location states that the optimum dosage in feed is 150ppm, along with it can be made use of in numerous feeds.

Production Method of Butylhydroxytoluene

(1) Put p-cresol and tert-butanol in a molar ratio of 1:1.1 into the reactor and heat to dissolve. Under the action of catalyst phosphoric acid, react under strong stirring at 65-70°C; after the reaction is completed, the reaction product is first washed with 10% sodium hydroxide solution until it is alkaline, and then washed with water until it is neutral; remove the solvent and recrystallize with ethanol That is the finished product. CH3C6H4OH+(CH3)3COH[H3PO4]→BHT

(2) Pass isobutylene into a mixture of 98% p-cresol and 2% concentrated sulfuric acid, and react at 65-70°C for 5 hours; wash off the acid with hot water at 60°C, and then wash with 10% NaOH and hot water successively until Neutral too rough. Dissolve the crude product in 50% hot ethanol, add 0.5% thiourea, filter while hot, spin dry, and dry to obtain the finished product with a yield of 90%-95%, a purity of 99.5%, and a melting point of >69.5°C.

In the sector, the main in addition to supporting towers are attached in collection. First consist of p-cresol as well as also vehicle driver right into the key tower in addition to the supporting tower, the temperature level of the key tower is handled at 65-80 ° C, and the temperature level of the complementary tower is regulated at 50-70 ° C. The isobutene gas is presented from all-time low of the major tower, and most of it responds with p-cresol generally tower, as well as also the continuing to be component comes out from the top of the major tower as well as gets in lowest level of the corresponding tower to even more respond with p-cresol. The action cycle of the main tower is taken care of within 4-5 hours. When the response mores than, stop the flow of isobutene gas, consist of 20% NaOH solution, as well as bubble with compressed gas. The counteracted alkylated product was split through a distillation column (8 academic plates) to get an unrefined thing. The last is liquified in 95% ethanol, ion-exchanged to get rid of inorganic salts, cooled to 10-20 ° C for formation, divided, in addition to vacuum-dried to acquire a thing with a melting point higher than 69 ° C.
CH3C6H4OH+( CH3) 2C CH2 [H2SO4] → BHT.

Butylhydroxytoluene Selection Principle

Compatibility
The compatibility between plastic polymers and Butylhydroxytoluene is often poor. Usually, the antioxidant is combined with the polymer melt at high temperature, and the antioxidant molecules are compatible in the middle of the polymer molecules when the polymer is solidified. Within the dosage range of the formula, the antioxidant should melt at the processing temperature. Special attention should be paid to the design of the formula, the melting point or upper limit of the melting range of the solid antioxidant and light stabilizer should not be lower than the processing temperature of the plastic polymer.

Migration
Plastic products, especially products with a small surface area to volume ratio (or mass ratio), oxidation mainly occurs on the surface of the product, which requires Butylhydroxytoluene to continuously migrate from the interior of the plastic product to the surface of the product to play its role. However, if the migration speed to the surface of the product is too fast and the amount of migration is too large, the antioxidant will volatilize into the environment on the surface of the product, or be lost in other media where the diffusing agent is in contact with the surface of the product. This loss is actually impossible. Avoid, take into account when designing formulations.

When there is a choice of antioxidant varieties, one should choose a variety with a relatively large molecular weight and a moderately high melting point, and the amount of antioxidants used should be determined on the premise of the most severe use environment.

Stability
Butylhydroxytoluene should remain stable in plastic materials, have little volatilization loss in the use environment and high temperature processing, do not change color or develop color, do not decompose (except for antioxidants used for processing heat stabilization), and do not mix with other additives Unfavorable chemical reactions occur, do not corrode mechanical equipment, and are not easily extracted by other substances on the surface of the product.

Processability
When processing plastic products, the addition of antioxidants may change the viscosity of the resin and the torque of the screw. If there is a large difference between the melting range of the antioxidant and the resin, the phenomenon of anti-oxidant bias flow or screw suppression will occur. When the melting point of Butylhydroxytoluene is 100℃ lower than the processing temperature, the antioxidant should be made into a certain masterbatch first, and then mixed with the resin to process the product, so as to avoid uneven distribution of the antioxidant in the product and a decrease in processing output due to bias flow.

Environment and sanitation
Butylhydroxytoluene should be non-toxic or low-toxic, dust-free or low-dust, have no harmful effect on human body, no harm to animals and plants, and no pollution to air, soil and water system during the processing, manufacturing and use of plastic products. For food packaging boxes, children’s toys, disposable infusions and other plastic products that are in direct or direct contact with the human body, not only antioxidants that have passed the inspection and approval of the US Food and Drug Administration (FDA), or are allowed by the European Community Commission regulations should be used. varieties, and the amount added should be strictly controlled within the maximum allowable limit.

About Products:
If you need Butylhydroxytoluene, a cosmetic raw material, please contact our service staff directly, and we will provide you with high-quality products at the best price.
As an experienced manufacturer and supplier of Butylhydroxytoluene, ZSpharmac will provide Butylhydroxytoluene raw materials to customers all over the world for a long time.
Over the years, the company has been adhering to the spirit of “integrity management, strict quality control, customer first”, and has won unanimous praise from domestic and foreign customers.

Company Profile and Corporate Culture

Company Profile:

ZhiShang Chemical is owned by ZhiShang Group is a professional new-type chemicals enterprise combined into research and development, production and sales .

The company’s competitive product is pharmaceutical raw materials and intermediates (especially carbohydrate derivatives Series), In recent years, the company has made a major breakthrough in food and feed additives, plant extraction, industrial chemicals industry .

The company insists on the spirit of “sincere management, strict quality control, customer as god” , get consistent high praise from customers at home and abroad.

Corporate Culture:

OUR MISSION
Help China Chemicals to benefit the happiness of human life
OUR VISSION
Become the most trusted chemical supplier in the world
OUR BUSINESS PHILOSOPHY
Striver – oriented, enrich employees, customer first, deep service, seek development
OUR VALUES
Be prepared for danger in times of peace, forge ahead actively, unity and cooperation, and be brave to fight

About Us

The production base is located in Zhangqiu chemical industry park and Tai’an high-tech chemical industry park. laboratory and workshop in strict accordance with the GMP standard and the product fit national ISO9001 and ISO2000 standards.

“Zhishang” products are exported to Europe, North and South America, the Middle East, Asia Pacific and Africa area, so as to establish a long-term and stable cooperation relationship with customer in the world.

Company Info
  • Business Type: Manufacturer
  • Product Range: Cosmetic raw materials
  • Products/Service:Cosmetic raw materials (flavors and fragrances,antioxidant products, moisturizing and hydrating, whitening agents, cosmetic additives)
  • Total Employees: 51~100
  • Capital (Million US $): 10000000RMB
  • Year Established: 2016
Production Capacity
  • No. of Production Lines : 8
  • No. of QC Staff : 5 -10 People
  • OEM Services Provided : yes
  • Factory Size (Sq.meters) : 3,000-5,000 square meters
  • Certificate: ISO9001 , CE , GMP , API , MSDS
  • Factory Location : Diao Town Industry Park, Zhangqiu City, Jinan City, Shandong Province, China.

Service

Pre-Sales Service

* Prompt reply and 24 hours online, professional team to provide best price and high quality product.

* Sample testing support.

* Every batch of products will be tested to ensureits quality.

*The packing also can be according the customers` requirment.

*Any inquiries will be replied within 24 hours.

*we provide Commerical Invoice, Packing List, Bill of loading, COA , Health certificate and Origin certificate. If your markets have any special requirements, let us know.

 

After-Sales Service

*The fact of logistics information monitoring.

* Any questions about the product can be consulted at any time.

*Product has any problem can return.

FAQ

Do you accept sample order?

We will make samples before mass production, and after sample approved, we’ll begin mass production. Doing 100% inspection during production, then do random inspection before packing.

 

HOW TO CONFIRM THE PRODUCT QUALITY BEFORE PLACING ORDERS?

You can get free samples for some products,you only need to pay the shipping cost or arrange a courier to us and take the samples. You can send us your product specifications and requests,we will manufacture the products according to your requests.

What’s your MOQ?

Our MOQ is 1kg. But usually we accept less quantity such as 100g on the condition that sample charge is 100% paid.

Do you supply product report?

Yes. We’ll give you product analysis report before shipping.

  Is there a discount?

Different quantity has different discount.

Shipping

1. ≤50kg, Express delivery recommended, usually called as DDU service;

2. ≤500kg, Air shipping recommended, usually called as FOB, CFR, or CIF service;

3. >500kg, sea shipping recommended, usually called as FOB, CFR, or CIF service;

4. For high value products, please select air shipping and express delivery for safe.

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