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Zhishang Chemical

Alpha-Hexylcinnamaldehyde CAS 101-86-0

Molecular Formula: C15H20O

Formula Weight: 216.32

ZSpharmac: Alpha-Hexylcinnamaldehyde Supplement

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Product Name: Alpha-Hexylcinnamaldehyde
CAS No: 101-86-0
Purity: 99%

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Basic Info

Product Name:Alpha-Hexylcinnamaldehyde
Other Names:A-Hexylcinnamaldehyde
Place of Origin:Shandong, China
Brand Name:ZSpharmac
Type:Cosmetic Raw Materials
Appearance:Clear Yellow Oil
EINECS No.:202-983-3
Provide:Alpha-Hexylcinnamaldehyde MSDS;
Alpha-Hexylcinnamaldehyde COA

What is Alpha-Hexylcinnamaldehyde?

Alpha-Hexylcinnamaldehyde (hexyl cinnamal) is a fragrance additive commonly used in fragrance and cosmetic industries. It occurs naturally in chamomile essential oil. It is a pale yellow to yellow liquid to solid that is practically insoluble in water but soluble in oil. Commercial materials usually contain small amounts of 2,6-di-tert-butyl-4-methoxyphenol as a stabilizer.

Alpha-Hexylcinnamaldehyde Properties:

Boiling point 174-176 °C/15 mmHg (lit.)
density 0.95 g/mL at 25 °C (lit.)
refractive index n20/D 1.55(lit.)
Fp 200 °F
storage temp. -20°C
solubility water: soluble0.005g/L at 25°C
form Oil
color Clear Yellow


Alpha-Hexylcinnamaldehyde Uses

  1. Alpha-Hexylcinnamaldehyde can be utilized in several day-to-day scent solutions, particularly in flower fragrances such as jasmine as well as gardenia, and the dose in day-to-day scents can be within 30%.
  2. Alpha-Hexylcinnamaldehyde is a food seasoning that is enabled to be used in GB 2760– 2001. Primarily utilized to prepare honey and also fruit tastes as well as blended spices.
  3. Alpha-Hexylcinnamaldehyde has a jasmine scent that is stronger as well as extra secure with a-amylcinnamaldehyde and fragrance. Made use of in soaps as well as detergents.
  4. Alpha-Hexylcinnamaldehyde extraction solvent. It is mainly used for the removal of oleoresin from different edible oils and also seasonings such as soybean, rice bran as well as cottonseed. GB 2760-96 defines food handling help.
  5. Alpha-Hexylcinnamaldehyde is a good basic material for formulating tree orchid oil. It is just one of one of the most floral selections of artificial fragrances. It likewise has a positive oily green scent, which can be much more dazzling when shown volatile floral scents. It can be used in flower essences such as jasmine and also magnolia, as well as can also be made use of in various other fragrance kinds. It can likewise be used in trace quantities of food tastes, such as honey as well as various fruit tastes.
  6. Alpha-Hexylcinnamaldehyde is a food taste permitted by my nation’s “Sanitary Standards for making use of Food Additives”. It is mostly made use of for the prep work of honey, fruit-type flavors as well as mixed tastes. The dosage is 6.5 mg/kg in candy; 2.6 mg/kg in chilly drinks; 2.4 mg/kg in baked goods; 0.8 mg/kg in sodas; 0.05 mg/kg in puddings.

Method for Synthesizing Alpha-Hexylcinnamaldehyde With Low Content of N-octanal

The function of the here and now development is precisely to the limitation of raw materials as well as processes existing in the prior art, suggests a chemical synthesis process of Alpha-Hexylcinnamaldehyde with affordable procedure, moderate response problems, and pure product scent, as well as offers 30% low-level n-octylaldehyde for oneself, made use of in the synthesis of Alpha-Hexylcinnamaldehyde, considerably minimizing the yield of organic solvents in the process of supplying n-octaldehyde for itself, attaining the objective of energy saving and cost reduction, as well as decreasing the by-product hexyl nonyl created by the self-condensation of n-octaldehyde at high web content Alkenal overcomes the shortcoming of the foul hexyl nonenal that limits the flower scent of the item, and makes the scent of the product pure and soft.
The technological issue to be fixed by the present development is accomplished with the following technical options:
The low-content n-octylaldehyde is straight made use of in the technique for manufacturing the initial Alpha-Hexylcinnamaldehyde, the condensation reaction of 30% n-octaldehyde as well as benzaldehyde is used to manufacture the initial hexyl cinnamaldehyde by one-step method. The response conditions are moderate as well as the item is easy to cleanse. Handling, the item fragrance is pure, the steps consist of:
a) Benzaldehyde, adding about 30% of n-octylaldehyde in the reactor in a molar ratio of 1:1 to 0.5, and afterwards adding a condensation stimulant in a proportion of 1 to 10% by weight of benzaldehyde;
b) open up the home heating and mixing reaction pot, heat up to 35 ~ 40 ℃, after the pot temperature level is steady, start to trickle the n-octaldehyde of 30% web content, control the reaction temperature level to 38 ℃ ~ 42 ℃, react under normal stress, 30% n-octaldehyde The dropwise addition amount is 1:1 ~ 0.5 (100% in n-octylaldehyde) by benzaldehyde mol proportion, and the including time is regulated at 4 ~ 6 hrs;
c) tasting and also testing after the dropwise enhancement is finished, when the n-octaldehyde web content is less than 0.5%, it is judged that the reaction is completed, as well as antarctic acetic acid is contributed to end the response, neutralized to pH 6.5 to 7.0 of the response system, split, and also the reduced layer water is divided;
d) move the item after water separation in step c) to the autoclave flash column, the temperature level on top of the column is 60 ~ 90 ℃, under the condition of vacuum pressure 1000 ~ 3000Pa, unreacted benzaldehyde and also n-octanol in the flash Total recovery and distillation, when the temperature level at the top of the tower goes down or does not release, the flash recovery of n-octanol ends;
e) move the unrefined product symphonious d) into the autoclave fixing tower, manage the tower top temperature 120 ~ 150 ℃, vacuum stress 133 ~ 1000Pa, reflux ratio 1:1 ~ 1:10 fractional distillation, get qualified item content 99.0 wt%.
The condensation driver added in the action a) is 1-10% potassium hydroxide or 1-10% sodium hydroxide.
The activator in the action a) is an enamel reactor.
When the material of n-octaldehyde detected in c) tasting described in step c) is above 0.5%, the response is continued with heat preservation as well as mixing until the web content of n-octaldehyde reaches below 0.5%.
The optimal reflux proportion in the step e) is 1:2 ~ 1:3.
The autoclave flash column and also the autoclave rectification column are specifically filled with BX500 and also cy700 stainless-steel cord corrugated cable mesh packings.
One more object of today development is to give a tool for directly synthesizing the very first Alpha-Hexylcinnamaldehyde with a reduced material of n-octylaldehyde, including a mixing container as well as a n-octylcinnamaldehyde gathering storage tank, and the mixing container is connected with the lye to a header tank and a benzaldehyde The total tank is gone through the very first chemical pump, and also the bottom of the lye top-level storage tank as well as the benzaldehyde total amount container is connected with the enamel response pot with the pipeline, and also the n-octaldehyde total tank is gotten in touch with the enamel reaction pot via the pipe [0015] Drop volume pump, The enamel response kettle is also connected with the antarctic acetic acid accumulating tank, the discharge port of the enamel response kettle is gotten in touch with the upright accumulating tank through the second chemical pump, and the upright gathering container is gotten in touch with the autoclave via the 3rd chemical pump The flash tower is connected, and the top of the autoclave flash tower is gotten in touch with the first gas-liquid separator via the very first spiral plate heat exchanger, and the first gas-liquid separator is all-time low of the autoclave flash tower and also the very first gas-liquid separator. The initial receiving tank is linked, the 4th chemical pump is connected with the autoclave rectification tower, the top of the autoclave rectification tower is gotten in touch with the 2nd gas-liquid separator with an additional spiral plate warm exchanger, the 2nd The gas-liquid separator is gotten in touch with the second receiving container. The top of the autoclave flash tower is connected with the initial gas-liquid separator with the initial spiral plate warmth exchanger, the very first gas-liquid separator is connected with the initial receiving tank, and the autoclave flashes The 4th chemical pump at the end of the steaming tower is connected with the autoclave correction tower, and also the top of the autoclave rectification tower is connected with the 2nd gas-liquid separator with the second spiral plate warm exchanger, as well as the 2nd gas-liquid separation The gadget is linked to the second receiving tank. The top of the autoclave flash tower is connected with the very first gas-liquid separator through the very first spiral plate warmth exchanger, the first gas-liquid separator is connected with the very first finding container, as well as the autoclave flashes The fourth chemical pump at the bottom of the steaming tower is connected with the autoclave correction tower, as well as the top of the autoclave rectification tower is gotten in touch with the 2nd gas-liquid separator through the secondary spiral plate warm exchanger, and the 2nd gas-liquid separation The gadget is linked to the 2nd finding storage tank. The top of the autoclave correction tower is connected with the 2nd gas-liquid separator via the secondary spiral plate heat exchanger, and the second gas-liquid separator is connected with the second receiving storage tank. The top of the autoclave correction tower is connected with the second gas-liquid separator with the additional spiral plate heat exchanger, as well as the 2nd gas-liquid separator is connected with the second receiving tank.
The advantageous results of the here and now development are as follows: the technical system of today development adopts benzaldehyde and also 30% n-octyl aldehyde as resources, and in the visibility of a catalyst, Alpha-Hexylcinnamaldehyde is synthesized under normal stress to obtain Alpha-Hexylcinnamaldehyde, and also after the n-octanol is recuperated by flash evaporation, the Rectification obtains a qualified item with a material of 99.0 wt%. For that reason, the technique of the development addresses the spin-off hexylnonenal generated by the self-condensation of n-octylaldehyde when the material is high, overcomes the imperfection that the smell of hexylnonenal prevents the scent of floral products, and has the advantages of reduced production cost, high purity of ended up products, and also fragrance. Pure personality.

Company Profile and Corporate Culture

Company Profile:

ZhiShang Chemical is owned by ZhiShang Group is a professional new-type chemicals enterprise combined into research and development, production and sales .

The company’s competitive product is pharmaceutical raw materials and intermediates (especially carbohydrate derivatives Series), In recent years, the company has made a major breakthrough in food and feed additives, plant extraction, industrial chemicals industry .

The company insists on the spirit of “sincere management, strict quality control, customer as god” , get consistent high praise from customers at home and abroad.

Corporate Culture:

Help China Chemicals to benefit the happiness of human life
Become the most trusted chemical supplier in the world
Striver – oriented, enrich employees, customer first, deep service, seek development
Be prepared for danger in times of peace, forge ahead actively, unity and cooperation, and be brave to fight

About Us

The production base is located in Zhangqiu chemical industry park and Tai’an high-tech chemical industry park. laboratory and workshop in strict accordance with the GMP standard and the product fit national ISO9001 and ISO2000 standards.

“Zhishang” products are exported to Europe, North and South America, the Middle East, Asia Pacific and Africa area, so as to establish a long-term and stable cooperation relationship with customer in the world.

Company Info
  • Business Type: Manufacturer
  • Product Range: Additive , Chemical Auxiliary & Catalyst , Organic Chemicals
  • Products/Service: Organic Intermediate,Inorganic Chemistry, APIs, Dyestuffs And Pigments, Fragrance And Spices, Food Additives
  • Total Employees: 51~100
  • Capital (Million US $): 10000000RMB
  • Year Established: 2016
Production Capacity
  • No. of Production Lines : 8
  • No. of QC Staff : 5 -10 People
  • OEM Services Provided : yes
  • Factory Size (Sq.meters) : 3,000-5,000 square meters
  • Certificate: ISO9001 , CE , GMP , API , MSDS
  • Factory Location : Diao Town Industry Park, Zhangqiu City, Jinan City, Shandong Province, China.


Pre-Sales Service

* Prompt reply and 24 hours online, professional team to provide best price and high quality product.

* Sample testing support.

* Every batch of products will be tested to ensureits quality.

*The packing also can be according the customers` requirment.

*Any inquiries will be replied within 24 hours.

*we provide Commerical Invoice, Packing List, Bill of loading, COA , Health certificate and Origin certificate. If your markets have any special requirements, let us know.


After-Sales Service

*The fact of logistics information monitoring.

* Any questions about the product can be consulted at any time.

*Product has any problem can return.


Do you accept sample order?

We will make samples before mass production, and after sample approved, we’ll begin mass production. Doing 100% inspection during production, then do random inspection before packing.



You can get free samples for some products,you only need to pay the shipping cost or arrange a courier to us and take the samples. You can send us your product specifications and requests,we will manufacture the products according to your requests.

What’s your MOQ?

Our MOQ is 1kg. But usually we accept less quantity such as 100g on the condition that sample charge is 100% paid.

Do you supply product report?

Yes. We’ll give you product analysis report before shipping.

  Is there a discount?

Different quantity has different discount.


1. ≤50kg, Express delivery recommended, usually called as DDU service;

2. ≤500kg, Air shipping recommended, usually called as FOB, CFR, or CIF service;

3. >500kg, sea shipping recommended, usually called as FOB, CFR, or CIF service;

4. For high value products, please select air shipping and express delivery for safe.

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