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Allyl Caproate CAS 123-68-2

Molecular Formula: C9H16O2

Formula Weight: 156.22

ZSpharmac: Allyl Caproate Supplier

Product Name: Allyl Caproate
CAS No: 123-68-2
Purity: 99%

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Basic Info

Product Name:Allyl Caproate
Other Names:Allyl Hexanoate
Place of Origin:Shandong, China
Brand Name:ZSpharmac
Type:Cosmetic Raw Materials
Appearance:Colorless to Almost Colorless Neat
EINECS No.:204-642-4
Storage:Room Temperature
Provide:Allyl Caproate MSDS;
Allyl Caproate COA

What is Allyl Caproate?

Allyl hexanoate, likewise referred to as pineapple aldehyde, also called pineapple aldehyde, nonadedehyde, is a colorless to a little yellow transparent liquid with a solid pineapple-like fruity aroma and a rum-like taste. It is a natural product. In pineapple, and so on. Pineapple aldehyde is recognized as GRAS by FEMA, FEMA number 2032, and also accepted for intake by FDA. my country’s GB2760-1996 specifies that it is a briefly allowed edible flavor. It is extensively used in the prep work of fruity flavors such as pineapple, apple, apricot, peach, wonderful orange, strawberry, and so on. Kind flavors, as well as liquor flavors such as rum and alcohol.

Allyl Caproate Property

Melting point 

-57.45°C (estimate)

Boiling point 

75-76 °C/15 mmHg (lit.)


0.887 g/mL at 25 °C (lit.)

vapor pressure 

2.69hPa at 25℃

refractive index 

n20/D 1.424(lit.)


151 °F

storage temp. 

Sealed in dry,Room Temperature






Colorless to Almost colorless


at 10.00 % in dipropylene glycol. sweet fruity pineapple tropical ethereal rum arrack fatty cognac

Odor Type


Water Solubility 



Allyl Caproate Application

Application 1. CN201810814434.3 divulges a feed flavor and its preparation technique. This product comes from the field of vet flavor manufacturing. The raw products made use of in the production of this item include: coumarin 10%-12%, diacetyl 8%- 10%, butyric acid 5%, vanillin 7%, ethyl acetate 5%, cinnamaldehyde 6%, allyl caproate 3%, hexanol 6%, ethyl vanillin 5%, rapeseed oil 43%, The process is as complies with: put the rapeseed oil of the formula right into the container, warm it to 70-75 ° C while mixing, add the coumarin as well as diacetyl as the major scent, butyric acid, vanillin, Ethyl acetate, cinnamaldehyde, Allyl Caproate, hexanol, stir well as well as respond for 25-27 minutes; stop home heating, cool down to space temperature, proceed mixing, include the formula amount of ethyl vanillin, stir for 12-14 mins, then stop Mix to get the finished item.

Application 2. CN201310589083.8 reveals a food emulsifier. Partially by weight, the development includes the complying with elements: glycerol monofatty acid ester: 4 to 6, sorbitan monostearate: 3 to 5, Sorbitol: 10 ~ 20, Sodium Citrate: 1 ~ 3, Geranyl Butyrate: 10 ~ 20, Allyl Caproate: 10 ~ 20, Glycerin: 20 ~ 30. Compared to the existing innovation, today invention has the complying with useful results: (1) good emulsification impact, wide range of uses, conveniently available basic materials, and low cost; (2) can be utilized for emulsification of cakes, cream, fructose, and so on.

Allyl Caproate Preparation

Report 1.
A type of manufacturing modern technology of Allyl Caproate is identified because: consist of the complying with actions:

A. Esterification: Hexanoic acid, allyl alcohol as well as p-toluenesulfonic acid are taken into the esterification pot symmetrical. Release the material from the top of the tower as well as wait till the leading temperature rises to 92 ° C. At the same time, 150L/hr of 2-methylbutyric acid and also 80L/hr of ethanol are presented from the high-level container, as well as the heavy steam stress of the esterification kettle is regulated to 0.5 Mpa;

B. Vacuum fractionation: The crude ester steamed from the esterification storage tank goes into the unrefined steamer with the oil-water separator for vacuum cleaner distillation. The vacuum cleaner level is controlled at -0.08 Mpa, the vapor stress is about 0.3 Mpa, and the temperature level of the storage tank is not less than 120 ° C. The temperature is regulated at 50-60 ° C, and the reduced boiling product (allyl alcohol) evaporated from the top of the tower is pumped right into the esterification pot;

C. Vacuum cleaner rectification: the low product of the still goes into the rectification kettle with the pump with the circulation meter, the vacuum cleaner level of the correction kettle is managed at -0.09 Mpa, the top temperature level is regulated at 110-115 ° C, as well as the ended up product steamed from the top of the tower goes through the flow meter via the pump Going into the allyl hexanoate finished item tank, the high boiling material (caproic acid) at the end of the distillation kettle is gone back to the esterification pot via a pump.

Report 2.
Include a certain amount of propylene alcohol as well as caproic acid to a four-necked container geared up with a thermometer, water separator, reflux condenser tube, and electrical stirrer.

(0.1 mol), hydroquinone (0.05 g), toluene as well as stimulant (nano rare earth composite superacid La3+/ SO42-/ TiO2), start the stirrer, control the temperature, reflux after a certain time period, allow stand, trendy, pour Out of the response option. The organic phases were divided, combined, washed and also dried. Add cuprous chloride to the filtrate for purification (0.05 g cuprous chloride/0.1 mol crude pineapple aldehyde), as well as collect the 186-188 ° C fraction to get the item.

Production Method of Allyl Caproate

(1) Solid acid catalysis technique. Include 23.2 g (0.4 mol) propenol, 23.2 g (0.2 mol) hexanoic acid, 0.1 g hydroquinone, 3.0 g solid extremely strong TiO2/SO2 -4, and likewise 30 mL toluene to a 150 mL flask. Heated to reflux for 1.5 h, in addition to the water produced by the response was protected by the entrainer toluene. The comments therapy is filteringed system after cooling down, as well as in addition the solid acid can be utilized regularly after being dried out. Include 0.1 g cuprous chloride to the filtrate and also after that simplify. 27.1 g of the 186-188 ° C portion is accumulated, which is allyl hexanoate. The refractive index is n20d1.4241, in addition to the return is 86.9%.
( 2) Sulfuric acid catalysis technique. Esterify allyl alcohol along with hexanoic acid under the catalysis of sulfuric acid. After the feedback is ended up, neat with water, afterwards combat with 15% Na2CO3 choice, afterwards clean with water up till neutral, include anhydrous sodium carbonate or anhydrous calcium chloride. Dry and dry, filter and additionally distill under decreased stress to get Allyl Caproate.

About Products:
If you need the cosmetic raw material Allyl Caproate, please contact our service staff directly, we will provide you with high-quality products at the best price.
Our company, as an experienced Allyl Caproate manufacturer and supplier, ZSpharmac will provide Allyl Caproate raw materials to customers around the world for a long time.
Over the years, the company has been adhering to the spirit of “integrity management, strict quality control, customer first”, and has won unanimous praise from domestic and foreign customers.

Company Profile and Corporate Culture

Company Profile:

ZhiShang Chemical is owned by ZhiShang Group is a professional new-type chemicals enterprise combined into research and development, production and sales .

The company’s competitive product is pharmaceutical raw materials and intermediates (especially carbohydrate derivatives Series), In recent years, the company has made a major breakthrough in food and feed additives, plant extraction, industrial chemicals industry .

The company insists on the spirit of “sincere management, strict quality control, customer as god” , get consistent high praise from customers at home and abroad.

Corporate Culture:

Help China Chemicals to benefit the happiness of human life
Become the most trusted chemical supplier in the world
Striver – oriented, enrich employees, customer first, deep service, seek development
Be prepared for danger in times of peace, forge ahead actively, unity and cooperation, and be brave to fight

About Us

The production base is located in Zhangqiu chemical industry park and Tai’an high-tech chemical industry park. laboratory and workshop in strict accordance with the GMP standard and the product fit national ISO9001 and ISO2000 standards.

“Zhishang” products are exported to Europe, North and South America, the Middle East, Asia Pacific and Africa area, so as to establish a long-term and stable cooperation relationship with customer in the world.

Company Info
  • Business Type: Manufacturer
  • Product Range: Cosmetic raw materials
  • Products/Service:Cosmetic raw materials (flavors and fragrances,antioxidant products, moisturizing and hydrating, whitening agents, cosmetic additives)
  • Total Employees: 51~100
  • Capital (Million US $): 10000000RMB
  • Year Established: 2016
Production Capacity
  • No. of Production Lines : 8
  • No. of QC Staff : 5 -10 People
  • OEM Services Provided : yes
  • Factory Size (Sq.meters) : 3,000-5,000 square meters
  • Certificate: ISO9001 , CE , GMP , API , MSDS
  • Factory Location : Diao Town Industry Park, Zhangqiu City, Jinan City, Shandong Province, China.


Pre-Sales Service

* Prompt reply and 24 hours online, professional team to provide best price and high quality product.

* Sample testing support.

* Every batch of products will be tested to ensureits quality.

*The packing also can be according the customers` requirment.

*Any inquiries will be replied within 24 hours.

*we provide Commerical Invoice, Packing List, Bill of loading, COA , Health certificate and Origin certificate. If your markets have any special requirements, let us know.


After-Sales Service

*The fact of logistics information monitoring.

* Any questions about the product can be consulted at any time.

*Product has any problem can return.


Do you accept sample order?

We will make samples before mass production, and after sample approved, we’ll begin mass production. Doing 100% inspection during production, then do random inspection before packing.



You can get free samples for some products,you only need to pay the shipping cost or arrange a courier to us and take the samples. You can send us your product specifications and requests,we will manufacture the products according to your requests.

What’s your MOQ?

Our MOQ is 1kg. But usually we accept less quantity such as 100g on the condition that sample charge is 100% paid.

Do you supply product report?

Yes. We’ll give you product analysis report before shipping.

  Is there a discount?

Different quantity has different discount.


1. ≤50kg, Express delivery recommended, usually called as DDU service;

2. ≤500kg, Air shipping recommended, usually called as FOB, CFR, or CIF service;

3. >500kg, sea shipping recommended, usually called as FOB, CFR, or CIF service;

4. For high value products, please select air shipping and express delivery for safe.

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